公开(公告)号：US10927315B2

公开(公告)日：2021-02-23

申请号：US16323710

申请日：2017-10-04

Applicant: SABIC Global Technologies B.V.

Inventor： Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Ravichander Narayanaswamy ,  Lara Galan-Sanchez

IPC: C10G69/06 ,  C07C4/22 ,  C10G1/00 ,  C10G1/10 ,  C10G9/36 ,  C10G45/00 ,  C10G51/06 ,  C10G69/00

Abstract: A process for producing olefins and aromatics comprising converting plastics to a hydrocarbon product comprising a gas phase and a liquid phase in a pyrolysis unit; separating the hydrocarbon product into a hydrocarbon gas stream comprising the gas phase and a hydrocarbon liquid stream comprising the liquid phase; feeding the hydrocarbon gas stream to a gas steam cracker to produce a gas steam cracker product comprising olefins, wherein an olefins amount in the gas steam cracker product is greater than in the hydrocarbon gas stream; separating the hydrocarbon liquid stream into a first fraction (b.p. 300° C.); feeding the first fraction to a liquid steam cracker to produce a liquid steam cracker product comprising olefins and aromatics, wherein an olefins amount in the liquid steam cracker product is greater than in the first fraction; and recycling the second fraction to the pyrolysis unit.

公开(公告)号：US10717936B2

公开(公告)日：2020-07-21

申请号：US16318464

申请日：2017-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Alexander Stanislaus ,  Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Santosh Ganji ,  Abrar A. Hakeem ,  Ashim Kumar Ghosh ,  Girish Koripelly ,  Mohammad Javeed

IPC: C10G1/10 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/85 ,  B29B17/04 ,  C10B53/07 ,  C10G11/18 ,  C10G45/02 ,  C10G69/06 ,  C10K1/00 ,  C10G45/58 ,  C10G1/08 ,  C10G1/00 ,  C10K1/32 ,  C10B57/06 ,  C10G47/00 ,  B29K27/00

Abstract: A process for processing mixed plastics comprising simultaneous pyrolysis and dechlorination of the mixed plastics, the process comprising contacting the mixed plastics with a zeolitic catalyst in a pyrolysis unit to produce a hydrocarbon product comprising a gas phase and a liquid phase; and separating the hydrocarbon product into a hydrocarbon gas stream and a hydrocarbon liquid stream, wherein the hydrocarbon gas stream comprises at least a portion of the gas phase of the hydrocarbon product, wherein the hydrocarbon liquid stream comprises at least a portion of the liquid phase of the hydrocarbon product, wherein the hydrocarbon liquid stream comprises one or more chloride compounds in an amount of less than about 100 ppmw chloride, based on the total weight of the hydrocarbon liquid stream, and wherein the hydrocarbon liquid stream is characterized by a viscosity of less than about 400 cP at a temperature of 300° C.

公开(公告)号：US10513661B2

公开(公告)日：2019-12-24

申请号：US16323191

申请日：2017-09-21

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Abrar A. Hakeem ,  Lara Galan-Sanchez ,  Nicolas Goyheneix ,  Santosh Ganji

IPC: C10G1/10 ,  C10G1/06 ,  C07C4/02 ,  C07C4/12 ,  C07C4/14 ,  B01D3/14 ,  B01D53/40 ,  B01D53/78 ,  C10B47/24 ,  C10B53/07 ,  C10B57/06 ,  C10G69/14

Abstract: A process for processing plastic waste comprising converting plastic waste to hydrocarbon liquid and a first C1-4 gas; contacting hydrocarbon liquid with a first hydroprocessing catalyst in hydroprocessing unit to yield a second C1-4 gas and a first hydrocarbon product comprising C5+ liquid hydrocarbons; introducing the first hydrocarbon product to a first separating unit to produce treated hydrocarbon stream comprising C5-8 hydrocarbons and a first heavies stream comprising C9+ hydrocarbons; contacting the first heavies stream with a second hydroprocessing catalyst in hydrodealkylating unit to yield a second hydrocarbon product comprising C5+ liquid hydrocarbons and a third C1-4 gas; conveying the second hydrocarbon product to the first separating unit; feeding treated hydrocarbon stream to steam cracker to produce steam cracker product; separating steam cracker product into olefin gas, saturated hydrocarbons gas, aromatics, and a second heavies stream; and conveying the second heavies stream to hydroprocessing unit.

公开(公告)号：US10442997B2

公开(公告)日：2019-10-15

申请号：US15636785

申请日：2017-06-29

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Lara Galan-Sanchez

IPC: C10G1/10 ,  C10G1/02 ,  C10G9/00 ,  C10G11/00 ,  C10G1/00 ,  C10G11/18 ,  C10G47/12

Abstract: Disclosed are methods of reduction of chlorine in pyrolysis products derived from a mixed plastics stream. Methods may comprise: (a) causing pyrolysis of a plastic feedstock to produce a first stream of C1-C4 gaseous hydrocarbons and light gas olefins and a second stream comprising the remaining pyrolysis components. The second stream and hydrogen gas may be fed into a hydrocracker to produce a third stream of gaseous C1-C4 hydrocarbon gases and a fourth stream comprising the remaining hydrocracker components. The fourth stream may be fed to either (i) a steam cracker to produce a fifth stream comprising C1-C4 gaseous hydrocarbons and light gas olefins, a sixth stream comprising C6-C8 hydrocarbons and a seventh stream comprising hydrocarbons heavier than C8; or (ii) a fluidized catalytic cracker to produce an eighth stream comprising C1-C4 gases and light gas olefins and a ninth stream comprising hydrocarbons that are C5 or greater.

公开(公告)号：US10858593B2

公开(公告)日：2020-12-08

申请号：US16467727

申请日：2018-01-03

Applicant: SABIC Global Technologies B.V.

Inventor： Krishna Kumar Ramamurthy ,  Ravichander Narayanaswamy ,  Venkata Ramanarayanan Ganapathy Bhotla ,  Alexander Stanislaus ,  Santosh Ganji

IPC: C07C2/66 ,  C07C6/04 ,  C07C6/10 ,  C10G1/00 ,  C07C4/06 ,  C08J11/12 ,  C10G1/10 ,  C07C11/06 ,  C07C15/04 ,  C07C15/085

Abstract: A process for producing cumene comprising converting plastics to hydrocarbon liquid and pyrolysis gas; feeding hydrocarbon liquid to hydroprocessor to yield hydrocarbon product and first gas stream; feeding hydrocarbon product to reforming unit to produce reforming product, second gas stream, and hydrogen; separating reforming product into non-aromatics recycle stream and second aromatics stream (C6+ aromatics); recycling non-aromatics recycle stream to reforming unit; separating second aromatics stream into benzene, C7, C8, C9, C10, and C11+ aromatics; contacting C7, C9, and/or C10 aromatics with a disproportionation&transalkylation catalyst/H2 to yield benzene&xylenes; conveying C11+ aromatics to hydroprocessor; introducing pyrolysis gas, first and/or second gas stream to first separator to produce first propylene stream, first C2&C4 unsaturated stream, and saturated gas (H2 and C1-4 saturated hydrocarbons); introducing first C2&C4 unsaturated stream to metathesis reactor to produce second propylene stream; and feeding benzene, and first and/or second propylene stream to alkylation unit to produce cumene.

公开(公告)号：US10829696B2

公开(公告)日：2020-11-10

申请号：US16319878

申请日：2017-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Mohammad Javeed ,  Alexander Stanislaus ,  Abrar A. Hakeem ,  Girish Koripelly ,  Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy

IPC: C10G1/10 ,  C10G25/05 ,  C10G1/00 ,  C10G55/04 ,  C10G55/06 ,  B29B17/04 ,  C10G1/08 ,  C10B53/07 ,  C10G11/18 ,  C10G55/02 ,  C10K1/32 ,  C10K1/00 ,  B29K27/00

Abstract: A process for dechlorination of a hydrocarbon stream and/or a hydrocarbon stream precursor comprising introducing the hydrocarbon stream and/or hydrocarbon stream precursor, a first zeolitic catalyst, and a stripping gas to a devolatilization extruder (DE) to produce an extruder effluent, wherein the hydrocarbon stream and/or hydrocarbon stream precursor comprises one or more chloride compounds in an amount of equal to or greater than about 10 ppm chloride, based on the total weight of the hydrocarbon stream and/or hydrocarbon stream precursor, and wherein the extruder effluent comprises one or more chloride compounds in an amount of less than the chloride amount in the hydrocarbon stream and/or hydrocarbon stream precursor.

公开(公告)号：US10563130B2

公开(公告)日：2020-02-18

申请号：US15315438

申请日：2015-07-13

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Sreenivasan Perinkulam Subramanian

IPC: C10G1/10 ,  C10G1/06 ,  C10G1/00 ,  C10G1/08

Abstract: Disclosed is a method for producing olefins and aromatic compounds from a hydrogen lean carbon containing feed, the method comprising hydropyrolyzing the hydrogen lean carbon containing feed in the presence of a hydrogen donor feed under reaction conditions sufficient to produce a product comprising olefins and aromatic compounds or a hydrocarbonaceous stream, wherein the hydrocarbonaceous stream is further processed into olefins and aromatic compounds, wherein the olefins and aromatic compounds from (i) or the hydrocarbonaceous stream from (ii) are each obtained by hydrogenation of the hydrogen lean carbon containing feed with the hydrogen donor feed and cracking of carbonaceous compounds comprised in the hydrogenated feed, and wherein the hydrogen donor feed comprises a compound that donates hydrogen to carbonaceous compounds in the hydrogen lean feed.

公开(公告)号：US10975313B2

公开(公告)日：2021-04-13

申请号：US16468071

申请日：2018-01-03

Applicant: SABIC Global Technologies B.V.

Inventor： Krishna Kumar Ramamurthy ,  Ravichander Narayanaswamy ,  Venkata Ramanarayanan Ganapathy Bhotla ,  Alexander Stanislaus ,  Santosh Ganji

IPC: C10G1/10 ,  C07C2/66 ,  C07C6/04 ,  C07C6/10 ,  B01J6/00 ,  B01J19/24 ,  B09B3/00 ,  C07C5/27 ,  C07C6/12 ,  C10B53/07 ,  C10G1/00 ,  C10G69/04

Abstract: A process for producing benzene and xylenes comprising introducing hydrocarbon liquid stream to hydroprocessor to yield first gas stream and hydrocarbon product (C5+); optionally introducing hydrocarbon product to first aromatics separating unit to produce saturated hydrocarbons (C5+) and first aromatics stream (C6+); feeding hydrocarbon product and/or saturated hydrocarbons to reformer to produce reformer product, second gas stream, and hydrogen stream; introducing reformer product to second aromatics separating unit to produce a non-aromatics recycle stream and second aromatics stream comprising C6+ aromatics; recycling non-aromatics recycle stream to reformer; introducing first aromatics stream and/or second aromatics stream to third aromatics separating unit to produce first C6 aromatics (benzene), C7 aromatics (toluene), C8 aromatics (xylenesðylbenzene), C9 aromatics, C10 aromatics, and C11+ aromatics; introducing C7 aromatics, C9 aromatics, C10 aromatics, or combinations thereof to disproportionation and transalkylation unit to yield third aromatics stream (benzene and xylenes); and conveying C11+ aromatics to hydroprocessor.

公开(公告)号：US20180002609A1

公开(公告)日：2018-01-04

申请号：US15636785

申请日：2017-06-29

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Lara Galan-Sanchez

IPC: C10G1/10 ,  C10G1/02 ,  C10G1/00 ,  C10G9/00 ,  C10G11/18 ,  C10G47/12

CPC classification number: C10G1/10 ,  C10G1/002 ,  C10G1/02 ,  C10G9/00 ,  C10G11/18 ,  C10G47/12 ,  C10G2400/20

Abstract: Disclosed are methods of reduction of chlorine in pyrolysis products derived from a mixed plastics stream. Methods may comprise: (a) causing pyrolysis of a plastic feedstock to produce a first stream of C1-C4 gaseous hydrocarbons and light gas olefins and a second stream comprising the remaining pyrolysis components. The second stream and hydrogen gas may be fed into a hydrocracker to produce a third stream of gaseous C1-C4 hydrocarbon gases and a fourth stream comprising the remaining hydrocracker components. The fourth stream may be fed to either (i) a steam cracker to produce a fifth stream comprising C1-C4 gaseous hydrocarbons and light gas olefins, a sixth stream comprising C6-C8 hydrocarbons and a seventh stream comprising hydrocarbons heavier than C8; or (ii) a fluidized catalytic cracker to produce an eighth stream comprising C1-C4 gases and light gas olefins and a ninth stream comprising hydrocarbons that are C5 or greater.

公开(公告)号：US11827857B2

公开(公告)日：2023-11-28

申请号：US17424665

申请日：2020-01-27

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Hatem Belfadhel ,  Girish Koripelly ,  Alexander Stanislaus ,  Krishna Kumar Ramamurthy ,  Krishnan Sankaranarayanan

IPC: C10G67/14 ,  C10G7/00 ,  C10G9/36 ,  C10G21/00 ,  C10G47/22

CPC classification number: C10G67/14 ,  C10G7/00 ,  C10G9/36 ,  C10G21/003 ,  C10G47/22 ,  C10G2300/107 ,  C10G2300/1033 ,  C10G2300/1077 ,  C10G2300/206 ,  C10G2300/4012 ,  C10G2300/44 ,  C10G2300/807 ,  C10G2400/20 ,  C10G2400/30

Abstract: Systems and methods for producing olefins and/or aromatics are disclosed. Methods disclosed includes thermal hydro-processing of crude oils and/or heavy oils and/or residues, in a thermal hydro-processing unit, to produce intermediate products, which can then be used to make valuable chemicals such as olefins and aromatics.