公开(公告)号：US09745235B2

公开(公告)日：2017-08-29

申请号：US15034937

申请日：2014-11-06

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Clark David Rea

IPC: C07C29/151 ,  C10K3/06 ,  C01B3/58 ,  B01J19/02 ,  C01B3/16 ,  B01J33/00 ,  B01J23/34 ,  B01J37/30 ,  C01B31/18 ,  B01J23/24 ,  B01J8/02 ,  C10K3/02 ,  B01J37/20 ,  B01J23/14 ,  B01J23/22

CPC classification number: C07C29/1518 ,  B01J8/02 ,  B01J19/02 ,  B01J23/14 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J33/00 ,  B01J37/20 ,  B01J2219/0286 ,  C01B3/16 ,  C01B3/58 ,  C01B32/40 ,  C01B2203/0435 ,  C01B2203/0475 ,  C01B2203/061 ,  C10K3/026 ,  C10K3/06 ,  Y02P20/52

Abstract: In an embodiment: a method of making syngas in a metal reactor can comprise introducing carbon dioxide and hydrogen to the metal reactor in the presence of a catalyst to form the syngas, wherein the metal reactor comprises nickel and wherein the carbon dioxide and the hydrogen are in physical contact with a wall of the metal reactor; and passivating the nickel with a sulfur containing compound.

公开(公告)号：US20160272562A1

公开(公告)日：2016-09-22

申请号：US15034937

申请日：2014-11-06

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Clark David Rea

IPC: C07C29/151 ,  C01B3/58

CPC classification number: C07C29/1518 ,  B01J8/02 ,  B01J19/02 ,  B01J23/14 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J33/00 ,  B01J37/20 ,  B01J2219/0286 ,  C01B3/16 ,  C01B3/58 ,  C01B32/40 ,  C01B2203/0435 ,  C01B2203/0475 ,  C01B2203/061 ,  C10K3/026 ,  C10K3/06 ,  Y02P20/52

Abstract: In an embodiment: a method of making syngas in a metal reactor can comprise introducing carbon dioxide and hydrogen to the metal reactor in the presence of a catalyst to form the syngas, wherein the metal reactor comprises nickel and wherein the carbon dioxide and the hydrogen are in physical contact with a wall of the metal reactor; and passivating the nickel with a sulfur containing compound.

Abstract translation: 在一个实施方案中：在金属反应器中制备合成气的方法可以包括在催化剂存在下将二氧化碳和氢气导入金属反应器以形成合成气，其中金属反应器包含镍，其中二氧化碳和氢是 与金属反应器的壁物理接触; 并用含硫化合物钝化镍。

公开(公告)号：US09850136B2

公开(公告)日：2017-12-26

申请号：US15028992

申请日：2014-10-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Clark David Rea

IPC: C07C29/151 ,  C07C29/04 ,  B01D53/86 ,  B01D53/96 ,  B01J37/02 ,  B01J23/26 ,  B01D53/70 ,  C01B31/20 ,  B01J38/12 ,  B01J21/04 ,  B01J23/92 ,  C01B32/50

CPC classification number: C01B32/50 ,  B01D53/70 ,  B01D53/8662 ,  B01D53/8668 ,  B01D53/96 ,  B01D2255/20784 ,  B01D2255/2092 ,  B01D2256/22 ,  B01D2257/2064 ,  B01D2257/702 ,  B01D2258/02 ,  B01J21/04 ,  B01J23/26 ,  B01J23/92 ,  B01J37/0201 ,  B01J38/12 ,  C07C29/04 ,  C07C29/1518 ,  Y02C20/20 ,  Y02P20/154 ,  Y02P20/584

Abstract: A process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a chromium oxide catalyst, wherein the stream comprises the CO2, and impurities, wherein the impurities comprise the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; forming a purified CO2 stream by interacting the impurities with the chromium oxide catalyst to form additional CO2 and chromium chloride; and regenerating the chromium oxide catalyst by contacting the chromium chloride with an oxygen containing gas stream.

公开(公告)号：US10005673B2

公开(公告)日：2018-06-26

申请号：US15028976

申请日：2014-10-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Shahid N. Shaikh ,  Clark David Rea ,  Xiankuan Zhang

IPC: C01B31/20 ,  B01D53/86 ,  B01J38/12 ,  B01J23/00 ,  B01J23/34 ,  B01J23/92 ,  C01B32/50 ,  B01J27/10

CPC classification number: C01B32/50 ,  B01D53/8687 ,  B01D2255/2047 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2094 ,  B01D2255/40 ,  B01D2256/22 ,  B01D2257/206 ,  B01D2257/702 ,  B01J23/002 ,  B01J23/34 ,  B01J23/92 ,  B01J27/10 ,  B01J38/12 ,  Y02P20/154 ,  Y02P20/584

Abstract: In one embodiment, a process for the purification of CO2 from chlorinated and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; interacting the impurities with the catalyst to form additional CO2 and metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream. In another embodiment, a process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the CO2 stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; oxidizing the impurities with catalyst oxygen to form additional CO2 and converting the chlorine to metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream.

公开(公告)号：US09714167B2

公开(公告)日：2017-07-25

申请号：US15116289

申请日：2015-03-31

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Shahid Shaikh ,  Clark David Rea

IPC: C01B3/00 ,  C01B3/38 ,  C10G2/00 ,  C10K3/02 ,  B01J23/889 ,  C01B31/18

CPC classification number: C01B3/00 ,  B01J23/8892 ,  C01B3/382 ,  C01B32/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0495 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/148 ,  C01B2203/86 ,  C10G2/32 ,  C10G2/33 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/1025 ,  C10K3/026 ,  Y02P20/142 ,  Y02P20/52 ,  Y02P30/30

Abstract: In an embodiment, a process of making C2+ hydrocarbons comprises contacting a feed comprising a methane steam reforming gas and an additional carbon dioxide with a manganese oxide-copper oxide catalyst to produce a product syngas in a contacting zone under isothermal conditions at a temperature of 620 to 650° C.; and converting the product syngas to C2+ hydrocarbons in the presence of a Fischer-Tropsch catalyst; wherein the methane steam reforming gas has an initial H2:CO volume ratio greater than 3; wherein the product syngas has a H2:CO volume ratio of 1.5 to 3; and wherein the contacting further comprises removing water.

公开(公告)号：US20160264424A1

公开(公告)日：2016-09-15

申请号：US15028992

申请日：2014-10-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Clark David Rea

IPC: C01B31/20 ,  B01D53/96 ,  B01J23/26 ,  C07C29/151 ,  B01J23/92 ,  B01J38/12 ,  C07C29/04 ,  B01D53/86 ,  B01J21/04

CPC classification number: C01B32/50 ,  B01D53/70 ,  B01D53/8662 ,  B01D53/8668 ,  B01D53/96 ,  B01D2255/20784 ,  B01D2255/2092 ,  B01D2256/22 ,  B01D2257/2064 ,  B01D2257/702 ,  B01D2258/02 ,  B01J21/04 ,  B01J23/26 ,  B01J23/92 ,  B01J37/0201 ,  B01J38/12 ,  C07C29/04 ,  C07C29/1518 ,  Y02C20/20 ,  Y02P20/154 ,  Y02P20/584

Abstract: A process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a chromium oxide catalyst, wherein the stream comprises the CO2, and impurities, wherein the impurities comprise the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; forming a purified CO2 stream by interacting the impurities with the chromium oxide catalyst to form additional CO2 and chromium chloride; and regenerating the chromium oxide catalyst by contacting the chromium chloride with an oxygen containing gas stream.

Abstract translation: 一种用于从氯化烃和非氯化烃净化二氧化碳的方法，包括：将CO 2流与氧化铬催化剂接触，其中流包含CO 2和杂质，其中杂质包含非氯化烃和氯化烃 碳氢化合物 通过使杂质与氧化铬催化剂相互作用以形成另外的CO 2和氯化铬来形成纯化的CO 2流; 以及通过使氯化铬与含氧气流接触来再生氧化铬催化剂。

公开(公告)号：US20160251226A1

公开(公告)日：2016-09-01

申请号：US15028976

申请日：2014-10-15

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Aghaddin Kh. Mammadov ,  Shahid N. Shaikh ,  Clark David Rea ,  Xiankuan Zhang

IPC: C01B31/20

CPC classification number: C01B32/50 ,  B01D53/8687 ,  B01D2255/2047 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2094 ,  B01D2255/40 ,  B01D2256/22 ,  B01D2257/206 ,  B01D2257/702 ,  B01J23/002 ,  B01J23/34 ,  B01J23/92 ,  B01J27/10 ,  B01J38/12 ,  Y02P20/154 ,  Y02P20/584

Abstract: In one embodiment, a process for the purification of CO2 from chlorinated and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; interacting the impurities with the catalyst to form additional CO2 and metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream. In another embodiment, a process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a metal oxide catalyst, wherein the CO2 stream comprises the CO2 and impurities comprising the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; oxidizing the impurities with catalyst oxygen to form additional CO2 and converting the chlorine to metal chloride; and regenerating the catalyst by contacting the metal chloride with an oxygen containing gas stream.

Abstract translation: 在一个实施方案中，从氯化和非氯化烃中净化CO 2的方法，包括：使CO 2流与金属氧化物催化剂接触，其中所述物流包含CO 2和包含非氯化烃和氯化烃的杂质; 使杂质与催化剂相互作用以形成额外的CO 2和金属氯化物; 并通过使金属氯化物与含氧气流接触来再生催化剂。 在另一个实施方案中，用于从氯化烃和非氯化烃净化CO 2的方法包括：将CO 2流与金属氧化物催化剂接触，其中CO 2流包含CO 2和包含非氯化烃和氯化物的杂质 碳氢化合物 用催化剂氧氧化杂质以形成额外的CO 2并将氯转化为金属氯​​化物; 并通过使金属氯化物与含氧气流接触来再生催化剂。