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1.发明授权公开(公告)号：US10106474B2
公开(公告)日：2018-10-23
申请号：US14171905
申请日：2014-02-04
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Jaap W. van Hal , Scott A. Stevenson , Jim Allman , David L. Sullivan , Travis Conant
Abstract: The disclosure is for a process for producing propylene and hexene (along with ethylene, pentenes, product butenes, heptenes and octenes) by metathesis from butenes (iso-, 1- and cis and trans 2-) and pentenes and then aromatizing the hexenes (along with higher olefins, such as heptenes and octenes) to benzene (along with toluene, xylenes, ethylbenzene and styrene). Since the desired products of the metathesis reaction are propylene and hexene, the feed to the metathesis reaction has a molar ratio for 1-butene:2-butene which favors production of propylene and 3-hexene with the concentration of hexenes and higher olefins in the metathesis product being up to 30 mole %. An isomerization reactor may be used to obtain the desired molar ratio of 1-butene:2-butene for the feed composition into the metathesis reactor. After the metathesis reaction, of hexene and higher olefins are separated for aromatization to benzene and other aromatics.
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2.发明授权Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolite 有权用于烃转化的催化剂，其制备方法及其使用方法-Ge沸石公开(公告)号：US09481617B2
公开(公告)日：2016-11-01
申请号：US14264441
申请日：2014-04-29
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
IPC: C07C2/12 , C07C5/32 , C07C1/20 , C07C5/41 , B01J29/04 , B01J29/83 , B01J29/85 , C07C2/24 , C07C2/66 , C07C2/76 , C07C6/12 , C10G35/095 , B01J29/84 , C07C2/42 , C07C5/31 , C07C5/367 , C10G35/09 , C10G35/085
CPC classification number: C07C1/20 , B01J29/047 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/42 , C07C2/66 , C07C2/76 , C07C5/31 , C07C5/367 , C07C5/412 , C07C5/417 , C07C6/123 , C07C6/126 , C07C2529/064 , C07C2529/44 , C07C2529/70 , C07C2529/74 , C07C2529/83 , C07C2529/85 , C10G35/085 , C10G35/09 , C10G35/095 , Y02P20/52 , C07C15/02
Abstract: In an embodiment a catalyst comprises a medium or large pore zeolite having germanium incorporated into the zeolite framework. The zeolite can have a pore structure that is one dimensional, two dimensional or three dimensional. A metal selected from Group 10 can be deposited on the zeolite. In an embodiment, a process for synthesizing the zeolite comprises preparing a medium pore zeolite containing germanium in the framework of the zeolite and calcining the zeolite. In an embodiment, the catalyst can be used in a process for the conversion of hydrocarbons comprising contacting a hydrocarbon stream containing alkanes, olefins, or mixtures thereof having 2 to 12 carbon atoms per molecule with the catalyst and recovering the product.
Abstract translation: 在一个实施方案中，催化剂包含掺入沸石骨架中的锗的中孔或大孔沸石。 沸石可以具有一维，二维或三维的孔结构。 选自组10的金属可以沉积在沸石上。 在一个实施方案中，合成沸石的方法包括在沸石的骨架中制备含有锗的中孔沸石并煅烧沸石。 在一个实施方案中，催化剂可用于烃的转化方法，包括使含有每分子具有2至12个碳原子的烷烃，烯烃或其混合物的烃流与催化剂接触并回收产物。
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3.发明申请CATALYST FOR CONVERSION OF HYDROCARBONS, PROCESS OF MAKING AND PROCESS OF USING THEREOF - GE ZEOLITE 有权碳氢化合物转化催化剂，其制备方法及其使用方法 - GE ZEOLITE公开(公告)号：US20150018590A1
公开(公告)日：2015-01-15
申请号：US14264441
申请日：2014-04-29
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Scott A. Stevenson , Alla K. Khanmamedova , Dustin B. Farmer , Scott F. Mitchell , Jim Vartuli
CPC classification number: C07C1/20 , B01J29/047 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/42 , C07C2/66 , C07C2/76 , C07C5/31 , C07C5/367 , C07C5/412 , C07C5/417 , C07C6/123 , C07C6/126 , C07C2529/064 , C07C2529/44 , C07C2529/70 , C07C2529/74 , C07C2529/83 , C07C2529/85 , C10G35/085 , C10G35/09 , C10G35/095 , Y02P20/52 , C07C15/02
Abstract: In an embodiment a catalyst comprises a medium or large pore zeolite having germanium incorporated into the zeolite framework. The zeolite can have a pore structure that is one dimensional, two dimensional or three dimensional. A metal selected from Group 10 can be deposited on the zeolite. In an embodiment, a process for synthesizing the zeolite comprises preparing a medium pore zeolite containing germanium in the framework of the zeolite and calcining the zeolite. In an embodiment, the catalyst can be used in a process for the conversion of hydrocarbons comprising contacting a hydrocarbon stream containing alkanes, olefins, or mixtures thereof having 2 to 12 carbon atoms per molecule with the catalyst and recovering the product.
Abstract translation: 在一个实施方案中，催化剂包含掺入沸石骨架中的锗的中孔或大孔沸石。 沸石可以具有一维，二维或三维的孔结构。 选自组10的金属可以沉积在沸石上。 在一个实施方案中，合成沸石的方法包括在沸石的骨架中制备含有锗的中孔沸石并煅烧沸石。 在一个实施方案中，催化剂可用于烃的转化方法，包括使含有每分子具有2至12个碳原子的烷烃，烯烃或其混合物的烃流与催化剂接触并回收产物。
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