公开(公告)号：US09206357B2

公开(公告)日：2015-12-08

申请号：US13895897

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy Hamilon ,  Corey William Radtke ,  Keith Michael Kreitman

IPC: C10G1/00 ,  C12P7/06 ,  C12P7/00 ,  C12P5/00 ,  C12F3/10 ,  C10G3/00 ,  C12P7/10 ,  C12P5/02 ,  C10G1/02

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for production and recovery of volatile organic compounds and higher hydrocarbons from biomass material. One embodiment comprises contacting a solid component of a biomass material with a digestive solvent to form a digested biomass stream, and at least a portion of the digested biomass is further thermocatalytically treated to generate higher hydrocarbons. The solid component is generated by a method comprising introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material; separating a vapor component and a solid component from the heated biomass material; retaining at least a portion of the gas component for use as part of the superheated vapor stream.

Abstract translation: 本发明的实施方案提供从生物质材料生产和回收挥发性有机化合物和高级烃。 一个实施方案包括将生物质材料的固体组分与消化溶剂接触以形成消化的生物质流，并且将至少一部分消化的生物质进一步热分解处理以产生更高级的烃。 固体组分通过包括将生物量材料引入无溶剂回收系统的隔室的方法产生，其中生物质材料含有一种或多种挥发性有机化合物; 使所述生物质材料与所述隔室中的过热蒸汽流接触以蒸发所述生物质材料中的初始液体含量的至少一部分; 从加热的生物质材料中分离出蒸汽组分和固体组分; 保留气体组分的至少一部分用作过热蒸气流的一部分。

公开(公告)号：US09242915B2

公开(公告)日：2016-01-26

申请号：US14572120

申请日：2014-12-16

Applicant: SHELL OIL COMPANY

Inventor： Corey William Radtke ,  Phillip Guy Hamilton ,  Keith Michael Kreitman

IPC: C07C29/80 ,  C07C29/76 ,  C12F3/10 ,  C10G3/00 ,  C12P7/10 ,  C10G1/00 ,  C10G1/02 ,  C10G1/04 ,  C07C29/82 ,  C10L1/182 ,  C10L10/02 ,  C12P7/14

CPC classification number: C07C29/76 ,  C07C29/80 ,  C07C29/82 ,  C10G1/002 ,  C10G1/02 ,  C10G1/04 ,  C10G3/46 ,  C10G3/50 ,  C10L1/182 ,  C10L10/02 ,  C10L2200/0469 ,  C10L2270/023 ,  C12F3/10 ,  C12P7/10 ,  C12P7/14 ,  Y02E50/16 ,  Y02E50/17 ,  Y02P30/20

Abstract: Embodiments of the present invention provide for production and recovery of ethanol or other volatile organic compounds, such as acetic acid, from solid biomass material. One embodiment comprises introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material, said superheated vapor stream comprising at least one volatile organic compound; separating a vapor component and a solid component from the heated biomass material, said vapor component comprising at least one volatile organic compound; and retaining at least a portion of the vapor component for use as part of the superheated vapor stream.

Abstract translation: 本发明的实施方案提供从固体生物质材料生产和回收乙醇或其它挥发性有机化合物，例如乙酸。 一个实施方案包括将生物质材料引入无溶剂回收系统的隔室中，其中生物质材料含有一种或多种挥发性有机化合物; 使所述生物质材料与所述隔室中的过热蒸汽流接触，以蒸发所述生物质材料中的初始液体含量的至少一部分，所述过热蒸气流包含至少一种挥发性有机化合物; 从加热的生物质材料中分离蒸汽组分和固体组分，所述蒸汽组分包含至少一种挥发性有机化合物; 并且保留至少一部分蒸汽组分以用作过热蒸气流的一部分。

公开(公告)号：US20130305598A1

公开(公告)日：2013-11-21

申请号：US13895897

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy HAMILTON ,  Corey William Radtke ,  Keith Michael Kreitman

IPC: C10G1/00

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for production and recovery of volatile organic compounds and higher hydrocarbons from biomass material. One embodiment comprises contacting a solid component of a biomass material with a digestive solvent to form a digested biomass stream, and at least a portion of the digested biomass is further thermocatalytically treated to generate higher hydrocarbons. The solid component is generated by a method comprising introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material; separating a vapor component and a solid component from the heated biomass material; retaining at least a portion of the gas component for use as part of the superheated vapor stream.

Abstract translation: 本发明的实施方案提供从生物质材料生产和回收挥发性有机化合物和高级烃。 一个实施方案包括将生物质材料的固体组分与消化溶剂接触以形成消化的生物质流，并且将至少一部分消化的生物质进一步热分解处理以产生更高级的烃。 固体组分通过包括将生物量材料引入无溶剂回收系统的隔室的方法产生，其中生物质材料含有一种或多种挥发性有机化合物; 使所述生物质材料与所述隔室中的过热蒸汽流接触以蒸发所述生物质材料中的初始液体含量的至少一部分; 从加热的生物质材料中分离出蒸汽组分和固体组分; 保留气体组分的至少一部分用作过热蒸气流的一部分。

公开(公告)号：US08946491B2

公开(公告)日：2015-02-03

申请号：US13895825

申请日：2013-05-16

Applicant: Shell Oil Company

Inventor： Corey William Radtke ,  Phillip Guy Hamilton ,  Keith Michael Kreitman

IPC: C07C29/80 ,  C07C29/76 ,  C12F3/10 ,  C10G3/00 ,  C12P7/10

CPC classification number: C07C29/76 ,  C07C29/80 ,  C07C29/82 ,  C10G1/002 ,  C10G1/02 ,  C10G1/04 ,  C10G3/46 ,  C10G3/50 ,  C10L1/182 ,  C10L10/02 ,  C10L2200/0469 ,  C10L2270/023 ,  C12F3/10 ,  C12P7/10 ,  C12P7/14 ,  Y02E50/16 ,  Y02E50/17 ,  Y02P30/20

Abstract: Embodiments of the present invention provide for production and recovery of ethanol or other volatile organic compounds, such as acetic acid, from solid biomass material. One embodiment comprises introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material, said superheated vapor stream comprising at least one volatile organic compound; separating a vapor component and a solid component from the heated biomass material, said vapor component comprising at least one volatile organic compound; and retaining at least a portion of the gas component for use as part of the superheated vapor stream.

Abstract translation: 本发明的实施方案提供从固体生物质材料生产和回收乙醇或其它挥发性有机化合物，例如乙酸。 一个实施方案包括将生物质材料引入无溶剂回收系统的隔室中，其中生物质材料含有一种或多种挥发性有机化合物; 使所述生物质材料与所述隔室中的过热蒸汽流接触，以蒸发所述生物质材料中的初始液体含量的至少一部分，所述过热蒸气流包含至少一种挥发性有机化合物; 从加热的生物质材料中分离蒸汽组分和固体组分，所述蒸汽组分包含至少一种挥发性有机化合物; 并且保留气体组分的至少一部分用作过热蒸气流的一部分。

公开(公告)号：US09624436B2

公开(公告)日：2017-04-18

申请号：US13895931

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy Hamilton ,  Corey William Radtke ,  Keith Michael Kreitman ,  Paul Richard Weider ,  Robert Lawrence Blackbourn

IPC: C12P7/00 ,  C10G1/00 ,  C12P7/06 ,  C12P5/00 ,  C12F3/10 ,  C10G3/00 ,  C12P7/10 ,  C12P5/02 ,  C10G1/02

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for efficient and economical production and recovery of ethanol or other volatile organic compounds. One embodiment comprises contacting a solid component of a biomass material with a solution adapted to facilitate saccharification. The solid component is generated by a method comprising: introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material; separating a vapor component and a solid component from the heated biomass material; and retaining at least a portion of the gas component for use as part of the superheated vapor stream. In one embodiment, the solid component contacted with the solution is further subjected to enzymatic hydrolysis and/or fermentation.

公开(公告)号：US09359557B2

公开(公告)日：2016-06-07

申请号：US13895882

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy Hamilton ,  Corey William Radtke ,  Keith Michael Kreitman

IPC: C12P7/06 ,  C12P7/08 ,  C10G1/00 ,  C12P7/00 ,  C12P5/00 ,  C12F3/10 ,  C10G3/00 ,  C12P7/10 ,  C12P5/02 ,  C10G1/02

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for efficient and economical production and recovery of ethanol or other volatile organic compounds, such as acetic acid, from solid biomass material, particularly on a larger scale, such as on the commercialization or industrial scale. According to one aspect of the invention, the method comprises (a) generating at least about 10 tons of prepared biomass material by adding a microbe, optionally an acid, and optionally, an enzyme to a solid biomass; (b) storing the prepared biomass material for at least about 24 hours in a storage facility to allow production of at least one volatile organic compound from at least a portion of the sugar in the solid biomass; and (c) capturing the at least one volatile organic compound by using a solventless recovery system.

Abstract translation: 本发明的实施方案提供了有效和经济地生产和回收来自固体生物质材料的乙醇或其它挥发性有机化合物，例如乙酸，特别是在商业化或工业规模上更大的规模。 根据本发明的一个方面，该方法包括（a）通过向固体生物质中加入微生物，任选的酸和任选的酶，产生至少约10吨的制备的生物质材料; （b）将所制备的生物质材料储存至少约24小时在储存设备中以允许从固体生物质中的糖的至少一部分产生至少一种挥发性有机化合物; 和（c）通过使用无溶剂回收系统捕获至少一种挥发性有机化合物。

公开(公告)号：US20130309735A1

公开(公告)日：2013-11-21

申请号：US13895882

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy HAMILTON ,  Corey William Radtke ,  Keith Michael Kreitman

IPC: C12P7/06

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for efficient and economical production and recovery of ethanol or other volatile organic compounds, such as acetic acid, from solid biomass material, particularly on a larger scale, such as on the commercialization or industrial scale. According to one aspect of the invention, the method comprises (a) generating at least about 10 tons of prepared biomass material by adding a microbe, optionally an acid, and optionally, an enzyme to a solid biomass; (b) storing the prepared biomass material for at least about 24 hours in a storage facility to allow production of at least one volatile organic compound from at least a portion of the sugar in the solid biomass; and (c) capturing the at least one volatile organic compound by using a solventless recovery system.

Abstract translation: 本发明的实施方案提供了有效和经济地生产和回收来自固体生物质材料的乙醇或其它挥发性有机化合物，例如乙酸，特别是在商业化或工业规模上更大的规模。 根据本发明的一个方面，该方法包括（a）通过向固体生物质中加入微生物，任选的酸和任选的酶，产生至少约10吨的制备的生物质材料; （b）将所制备的生物质材料储存至少约24小时在储存设备中以允许从固体生物质中的糖的至少一部分产生至少一种挥发性有机化合物; 和（c）通过使用无溶剂回收系统捕获至少一种挥发性有机化合物。

公开(公告)号：US20130309727A1

公开(公告)日：2013-11-21

申请号：US13895931

申请日：2013-05-16

Applicant: SHELL OIL COMPANY

Inventor： Phillip Guy Hamilton ,  Corey William Radtke ,  Keith Michael Kreitman ,  Paul Richard Weider ,  Robert Lawrence Blackbourn

IPC: C12P7/00

CPC classification number: C10G1/002 ,  C10G1/02 ,  C10G3/46 ,  C10G3/50 ,  C12F3/10 ,  C12P5/00 ,  C12P5/02 ,  C12P5/026 ,  C12P7/00 ,  C12P7/06 ,  C12P7/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678

Abstract: Embodiments of the present invention provide for efficient and economical production and recovery of ethanol or other volatile organic compounds. One embodiment comprises contacting a solid component of a biomass material with a solution adapted to facilitate saccharification. The solid component is generated by a method comprising: introducing a biomass material to a compartment of a solventless recovery system, wherein the biomass material contains one or more volatile organic compounds; contacting the biomass material with a superheated vapor stream in the compartment to vaporize at least a portion of an initial liquid content in the biomass material; separating a vapor component and a solid component from the heated biomass material; and retaining at least a portion of the gas component for use as part of the superheated vapor stream. In one embodiment, the solid component contacted with the solution is further subjected to enzymatic hydrolysis and/or fermentation.

Abstract translation: 本发明的实施方案提供有效和经济地生产和回收乙醇或其它挥发性有机化合物。 一个实施方案包括使生物质材料的固体组分与适于促进糖化的溶液接触。 固体组分通过以下方法产生：包括：将生物质材料引入到无溶剂回收系统的隔室中，其中所述生物质材料含有一种或多种挥发性有机化合物; 使所述生物质材料与所述隔室中的过热蒸汽流接触以蒸发所述生物质材料中的初始液体含量的至少一部分; 从加热的生物质材料中分离出蒸汽组分和固体组分; 并且保留气体组分的至少一部分用作过热蒸气流的一部分。 在一个实施方案中，与溶液接触的固体组分进一步进行酶水解和/或发酵。