公开(公告)号：US11038196B2

公开(公告)日：2021-06-15

申请号：US16333316

申请日：2017-09-12

Applicant: SOLVAY SA

Inventor： Stephen E. Burkhardt ,  Kostantinos Kourtakis ,  Brian Levy-Polis

IPC: H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58

Abstract: Disclosed herein are electrolyte compositions comprising at least one electrolyte component comprising a cyclic carbonate, such as a fluoroethylene carbonate, and at least one additive comprising a 6-member ring heterocyclic sulfate, such as a 1,3 propylene sulfate. The disclosed electrolyte compositions can comprise additional electrolyte components, such as fluorinated acyclic carboxylic acid esters, and additional additives, such as lithium boron compounds, and cyclic carboxylic acid anhydrides, such as maleic anhydride. The improved battery performances, which include high temperature cycling conditions and/or room temperature stability, make these electrolyte compositions useful in electrochemical cells, such as lithium ion batteries.

公开(公告)号：US11489198B2

公开(公告)日：2022-11-01

申请号：US16326466

申请日：2017-07-27

Applicant: SOLVAY SA

Inventor： Kenneth Gene Moloy ,  Stephen E. Burkhardt ,  Kostantinos Kourtakis ,  Brian Levy-Polis

IPC: H01M10/0567 ,  H01M10/0569 ,  C07F7/18 ,  H01M10/0568 ,  H01M10/0525

Abstract: Disclosed herein are electrolyte compositions comprising a fluorinated solvent, at least one silyl oxalate represented by the formulas RR′Si(C2O4), wherein R and R′ are each the same or different from each other and independently selected from C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, or C6-C10 aryl radical, optionally comprising at least one substituent selected from halogen, hydroxyl, alkoxy, carbonyl, and carboxyl groups; and LiPF6. Also disclosed herein are electrolyte compositions comprising a fluorinated solvent and a lithium oxalato phosphate salt represented by the formula LiPF(6-2q)(C2O4)q, wherein q is 1, 2 or 3; wherein the oxalato phosphate salt comprises at least a portion that is derived from at least one silyl oxalate as defined herein. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

公开(公告)号：US11289738B2

公开(公告)日：2022-03-29

申请号：US15749807

申请日：2016-06-03

Applicant: SOLVAY SA

Inventor： Samuel David Arthur ,  Stephen E. Burkhardt ,  Kostantinos Kourtakis ,  Brian Levy-Polis ,  Jun J. Liu ,  Mark Gerrit Roelofs

IPC: H01M10/0568 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M4/131 ,  H01M4/02

Abstract: Described herein are: An electrolyte composition comprising a) a fluorinated solvent for an electrolyte salt; b) an oxalate salt represented by the Formula LiPF(6-2q)(Ox)q, wherein Ox is an oxalate moiety and q is 1, 2 or 3; and c) optionally, at least one electrolyte salt. In some embodiments, the electrolyte composition comprises a mole ratio of Ox/P in the range of from 0.001 to 5. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.