公开(公告)号：US09458084B2

公开(公告)日：2016-10-04

申请号：US14400422

申请日：2013-05-07

Applicant: SOLVAY SA

Inventor： Janis Jaunzems

IPC: C07C67/343 ,  C07C69/738 ,  A01N37/06

CPC classification number: C07C67/343 ,  A01N37/06 ,  C07C69/738

Abstract: The present disclosure relates to compounds of the formula wherein R2 and A are certain substituents, Y is an ester group, a nitrile group or an amido group and Z is O, S or N+R2, and which compounds are, for example, useful as intermediates for pyrazole fungicides. The compounds of the present disclosure can be prepared by the reaction of a compound of formula R2—C(O)—CH2Y, with an orthoformate HC—(OR3)3 in the presence of a base, especially in the presence of an amine, e.g. triethylamine.

公开(公告)号：US20150126765A1

公开(公告)日：2015-05-07

申请号：US14400422

申请日：2013-05-07

Applicant: SOLVAY SA

Inventor： Janis Jaunzems

IPC: C07C67/343 ,  A01N37/06

CPC classification number: C07C67/343 ,  A01N37/06 ,  C07C69/738

Abstract: Compounds of the formula (I) wherein R2, A are certain substituents, Y is an ester group, a nitrile group or an amido group and Z is O, S or N′R2, and which compounds are, for example, useful as intermediates for pyrazole fungicides, can be prepared by the reaction of a compound of formula R2—C(O)—CH2Y, with an orthoformate HC—(OR3)3 in the presence of a base, especially in the presence of an amine, e.g. triethylamine

Abstract translation: 式（I）的化合物，其中R2，A为某些取代基，Y为酯基，腈基或酰胺基，Z为O，S或N'R2，哪些化合物可用作中间体 对于吡唑杀真菌剂，可以通过式R 2 -C（O）-CH 2 Y的化合物与原甲酸酯HC-（OR 3）3在碱的存在下，特别是在胺的存在下反应来制备，例如 三乙胺

公开(公告)号：US10829456B2

公开(公告)日：2020-11-10

申请号：US16071677

申请日：2017-01-27

Applicant: SOLVAY SA

Inventor： Suzanne Wassmann ,  Janis Jaunzems ,  Stefan Mross ,  Jean Fabre

IPC: C07D231/18 ,  C07C225/14 ,  C07D231/12

Abstract: The present invention concerns new halogen substituted diketone compounds, new pyrazole compounds, processes for the manufacture of pyrazole compounds and processes for the manufacture of agrochemical or pharmaceutical compounds.