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公开(公告)号：US10059656B2
公开(公告)日：2018-08-28
申请号：US15104822
申请日：2014-12-19
Inventor： Mansour I. Taftaf , Jaiprakash Brijlal Sainani , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Vimalkumar Mahendrabhai Patel , Sergei Andreevich Sergeev , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts , Nourdin Ghalit
IPC: C07C233/69 , C07C235/48 , C07C233/18 , C08F110/06 , B01J31/02
CPC classification number: C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
Abstract: A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.
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公开(公告)号：US09688790B2
公开(公告)日：2017-06-27
申请号：US14410248
申请日：2013-06-24
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Mansour Taftaf , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts , Jaiprakash Brijlal Sainani , Vimalkumar Mahendrabhai Patel , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Sergei Andreevich Sergeev , Nourdin Ghalit
IPC: C08F110/06 , C07C233/18 , C07C233/69 , C07C235/48
CPC classification number: C08F110/06 , C07C233/18 , C07C233/69 , C07C235/48 , C07C2101/14 , C07C2601/14 , C07C2601/16 , C08F10/06 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/651 , C08F4/6465 , C08F4/6565
Abstract: The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.
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公开(公告)号：US20160176998A1
公开(公告)日：2016-06-23
申请号：US14911028
申请日：2014-08-11
Applicant: Martin Alexander ZUIDEVELD , Jaiprakash Brijlal SAINANI , Mahendrabhai Patel VIMALKUMAR , SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V.
IPC: C08F210/16 , C07F7/02
CPC classification number: C08F210/06 , C07F7/025 , C08F210/16 , C08F4/6465 , C08F4/6565 , C08F2500/12 , C08F2500/15
Abstract: The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.
Abstract translation: 本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I结构的化合物：Si（L）n（OR 11）4-n（ 式I），其中Si是价态为4+的硅原子; O是具有2-价的氧原子，O经由硅 - 氧键与Si键合; n为1,2,3或4; R11选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; L是由式（II）表示的基团，其中L通过氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自IUPAC元素周期表的第13,14,15,16或17族的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表IUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基 原子，任选地含有选自IUPAC元素周期表的第13,14,15,16或7族的杂原子。
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公开(公告)号：US20170283531A1
公开(公告)日：2017-10-05
申请号：US15625679
申请日：2017-06-16
IPC: C08F210/06 , C08F210/16 , C07F7/02
CPC classification number: C08F210/06 , C07F7/025 , C08F210/16 , C08F4/6465 , C08F4/6565 , C08F2500/12 , C08F2500/15
Abstract: The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4−n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by Formula II wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements.
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公开(公告)号：US09701773B2
公开(公告)日：2017-07-11
申请号：US14911028
申请日：2014-08-11
IPC: C08F210/16 , C07F7/02
CPC classification number: C08F210/06 , C07F7/025 , C08F210/16 , C08F4/6465 , C08F4/6565 , C08F2500/12 , C08F2500/15
Abstract: The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.
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Patent Agency Ranking
公开(公告)号：US09587051B2
公开(公告)日：2017-03-07
申请号：US14762500
申请日：2014-01-28
Applicant: Saudi Basic Industries Corporation
Inventor： Mansour Taftaf , Jaiprakash Brijlal Sainani , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Vimalkumar Mahendrabhai Patel , Sergei Andreevich Sergeev , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts
IPC: C08F4/654 , C08F4/655 , C08F4/656 , C08F110/06 , C07C233/23 , C07C233/18 , C08F4/649 , C08F10/06 , C07C233/69
CPC classification number: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
Abstract: A process for preparing a catalyst component, including: contacting a compound R9zMgX2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; contacting the first intermediate reaction product with at least one activating compound selected electron donors, compounds of formula M(OR10)v-w(OR11)w, wherein M is Ti, Zr, Hf, Al or Si, and M(OR10)v-w(R11)w wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v is 3 or 4, and w is less than v, to give a second intermediate reaction product; and contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, and a 1,3-diether as an internal electron donor.
Abstract translation: 一种催化剂组合物，其包含单酯，由式（I）表示的作为内电子给体的化合物，以及任选的另外的选自二酯和二醚的内给电子体，其中：R1，R2，R3，R4，R5和 R6是氢，具有至多20个碳原子的直链，支链和环状烷基，以及具有6至20个碳原子的芳族取代和未取代的烃基，R7是具有至多20个碳原子的直链，支链和环状烷基，芳基取代和未取代的烃基 具有6至20个碳原子，并且R 8是具有6至20个碳原子的芳族取代和未取代的烃基。 还描述了制备聚合催化剂组合物的方法，包含催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系; 以及催化剂体系用于烯烃聚合的用途。
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公开(公告)号：US20130172595A1
公开(公告)日：2013-07-04
申请号：US13723923
申请日：2012-12-21
Applicant: Saudi Basic Industries Corporation
IPC: C07F7/18
CPC classification number: C07F7/1876 , C07F7/1888
Abstract: The present invention relates to a method for preparing di-organo-dialkoxysilanes, in particular di-organo-dialkoxysilanes wherein one or both of the organic substituents are bulky. The method comprises reacting a tetraalkoxysilane compound with a first Grignard reagent to form a mono-organo-tri-alkoxysilane compound, which is then reacted with a chlorinating agent to form a chlorinated mono-organo-di-alkoxysilane which is then reacted with a second Grignard reagent to form the di-organo-di-alkoxysilane compound.
Abstract translation: 本发明涉及二有机 - 二烷氧基硅烷的制备方法，特别是二有机 - 二烷氧基硅烷，其中一个或两个有机取代基是体积大的。 该方法包括使四烷氧基硅烷化合物与第一格氏试剂反应形成单有机三烷氧基硅烷化合物，然后与氯化剂反应形成氯化的单有机二烷氧基硅烷，然后与第二格 格氏试剂，形成二有机二烷氧基硅烷化合物。
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公开(公告)号：US09663596B2
公开(公告)日：2017-05-30
申请号：US14762279
申请日：2014-01-28
Applicant: Saudi Basic Industries Corporation
Inventor： Mansour Taftaf , Jaiprakash Brijlal Sainani , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Vimalkumar Mahendrabhai Patel , Sergei Andreevich Sergeev , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts
IPC: C08F110/06 , C07C233/23 , C07C233/18 , C07C233/69 , C08F4/655 , C08F4/649 , C08F4/654 , C08F10/06
CPC classification number: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
Abstract: A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
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公开(公告)号：US20150368381A1
公开(公告)日：2015-12-24
申请号：US14762500
申请日：2014-01-28
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai Patel , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS
IPC: C08F110/06
CPC classification number: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
Abstract: A process for preparing a catalyst component, including:contacting a compound R9zMgX2−z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product;contacting the first intermediate reaction product with at least one activating compound selected electron donors, compounds of formula M(OR10)v-w(OR11)w, wherein M is Ti, Zr, Hf, Al or Si, and M(OR10)v-w(R11)w wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v is 3 or 4, and w is less than v, to give a second intermediate reaction product; andcontacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, and a 1,3-diether as an internal electron donor.
Abstract translation: 一种制备催化剂组分的方法，包括：使化合物R9zMgX2-z与其中R9是芳族的，含有至多20个碳原子的脂族或环脂族基团接触，X是卤化物，z大于0且小于2， 与含烷氧基或芳氧基的硅烷化合物反应，得到第一中间反应产物; 使第一中间反应产物与至少一种活化化合物选择的电子给体，式M（OR10）vw（OR11）w的化合物，其中M是Ti，Zr，Hf，Al或Si，以及M（OR10）vw ）w，其中M是Si，每个R 10和R 11独立地表示烷基，烯基或芳基，v是M的化合价，v是3或4，w小于v，得到第二中间反应产物 ; 并使第二中间反应产物与含卤素的Ti化合物，单酯作为活化剂和作为内部电子给体的1,3-二醚接触。
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公开(公告)号：US20150259448A1
公开(公告)日：2015-09-17
申请号：US14410248
申请日：2013-06-24
Applicant: SAUDI BASIC INDUSTRIES CORPORATION
Inventor： Mansour Taftaf , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts , Jaiprakash Brijlal Sainani , Vimalkumar Mahendrabhai Patel , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Sergei Andreevich Sergeev , Nourdin Ghalit
IPC: C08F110/06 , C07C233/18 , C07C235/48 , C07C233/69
CPC classification number: C08F110/06 , C07C233/18 , C07C233/69 , C07C235/48 , C07C2101/14 , C07C2601/14 , C07C2601/16 , C08F10/06 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/651 , C08F4/6465 , C08F4/6565
Abstract: The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.
Abstract translation: 本发明涉及一种催化剂组合物，其包含由式（I）的费休投影表示的化合物作为内电子给体，（I）其中：R1，R2，R3，R4，R5和R6相同或不同， 独立地选自氢，直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; R 7选自直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基; N是氮原子; O是氧原子; C是碳原子。 本发明还涉及制备所述聚合催化剂组合物的方法和包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。 此外，本发明涉及通过本发明的方法获得的聚烯烃以及式（I）化合物在内电子给体中用于烯烃聚合的催化剂中的用途。
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