公开(公告)号：US10336615B2

公开(公告)日：2019-07-02

申请号：US15389666

申请日：2016-12-23

Applicant: Shenzhen Institutes of Advanced Technology

Inventor： Huaiyu Wang ,  Yuetao Zhao ,  Xuefeng Yu

IPC: C01B25/00 ,  A61K41/00 ,  H01L51/00 ,  C07F9/06 ,  C09K15/14 ,  C09K15/28 ,  C07C309/04 ,  C07C309/06 ,  C07C309/29 ,  C07C309/30 ,  C07C309/39 ,  C07C309/40 ,  C07C309/42 ,  C07C309/46 ,  H01L51/05 ,  H01L51/50

Abstract: The present invention provides a titanium ligand-modified black phosphorus and the preparation method and use thereof. The titanium ligand-modified black phosphorus is a complex of black phosphorus and a titanium ligand having a structure represented by formula (I): wherein in the formula (I), R1 comprises C1-C6 alkyl, or phenyl optionally further substituted with 0 to 5 groups each independently selected from halogen atom, C1-C6 alkyl, nitro, hydroxy, amino or C1-C3 alkoxy; the C1-C6 alkyl or C1-C3 alkoxy is optionally further substituted with 0 to 3 groups each independently selected from halogen atom, nitro, hydroxy, amino, methyl, ethyl or n-propyl. The titanium ligand-modified black phosphorus of the present invention is not likely oxidized without changing inherent properties of the black phosphorus, and the antioxidant capacity is greatly enhanced.