公开(公告)号：US20100266799A1

公开(公告)日：2010-10-21

申请号：US12668500

申请日：2008-07-09

Applicant: William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

Inventor： William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

IPC: C08G18/10 ,  C08G18/34 ,  B32B1/08

CPC classification number: C08G18/4288 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/4833 ,  C08G18/4841 ,  C08G2101/0008 ,  C08J9/30 ,  C08J2375/04 ,  Y10T428/139 ,  C08G18/3275 ,  C08G18/3206 ,  C08G18/40

Abstract: A prepolymer or elastomer is the reaction product of reactants (a) at least one polyester polyol or fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about 45 weight percent monounsaturated fatty acids or derivatives thereof, (b) optionally, at least one polyol which is different from the polyol of (a); and (c) at least one isocyanate compound (herein after isocyanate) having an average of at least about 1.8 isocyanate groups per molecule. A process comprises admixing reactants (a) at least one polyol composition comprising the fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about any of 45 weight percent monounsaturated fatty acids or derivatives thereof; and (b) at least one isocyanate having an average functionality of at least about 1.8 under reaction conditions to form a reaction product which is an elastomer or prepolymer is formed therefrom. An article, coating or thermoplastic polyurethane comprises the elastomer is formed from the prepolymer of or using the process of the invention.

Abstract translation: 预聚物或弹性体是反应物（a）至少一种聚酯多元醇或脂肪酸衍生多元醇的反应产物，其是至少一种引发剂与脂肪酸或包含至少约45重量％的脂肪酸​​的衍生物的混合物的反应产物 百分比的单不饱和脂肪酸或其衍生物，（b）任选的至少一种不同于（a）的多元醇的多元醇; 和（c）每分子平均具有至少约1.8个异氰酸酯基团的至少一种异氰酸酯化合物（本文中为异氰酸酯）。 一种方法包括混合反应物（a）至少一种多元醇组合物，其包含脂肪酸衍生的多元醇，其是至少一种引发剂的反应产物和脂肪酸或脂肪酸的混合物的混合物，其至少包含约45重量％的单不饱和物 脂肪酸或其衍生物; 和（b）在反应条件下至少一种具有至少约1.8的平均官能度的异氰酸酯形成由弹性体或预聚物形成的反应产物。 一种制品，涂层或热塑性聚氨酯包括弹性体由本发明的预聚物或使用本发明的方法形成。

公开(公告)号：US07745652B2

公开(公告)日：2010-06-29

申请号：US12328868

申请日：2008-12-05

Applicant: Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

Inventor： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC: C07C51/43

CPC classification number: C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

Abstract: Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

Abstract translation: 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20080023884A1

公开(公告)日：2008-01-31

申请号：US11879120

申请日：2007-07-16

Applicant: Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

Inventor： Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

IPC: B29C45/03 ,  C08G61/08

CPC classification number: C08G61/08 ,  C08F6/006

Abstract: Crosslinked polydicyclopentadiene polymer and copolymer are made by first forming a thermoplastic polymeric intermediate in a ring-opening metathesis polymerization (ROMP), and then crosslinking the intermediate in a melt-processing or solution processing step. The formation of the intermediate permits facile removal of residual monomer, which leads to a reduction in odor and improvement in physical properties. Crosslinking can be achieved using various crosslinking strategies, including further ROMP reactions, addition polymerization of residual double bonds, addition of a crosslinking agent or introduction of functional groups.

Abstract translation: 交联的聚二聚环戊二烯聚合物和共聚物通过首先在开环易位聚合（ROMP）中形成热塑性聚合物中间体，然后在熔融加工或溶液处理步骤中交联中间体来制备。 中间体的形成允许容易地去除残留的单体，这导致气味的降低和物理性能的改善。 可以使用各种交联策略实现交联，包括进一步的ROMP反应，残余双键的加成聚合，加入交联剂或引入官能团。

公开(公告)号：US20050154221A1

公开(公告)日：2005-07-14

申请号：US10508805

申请日：2003-04-17

Applicant: Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

Inventor： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

IPC: B01J31/24 ,  C07B61/00 ,  C07C6/04 ,  C07C11/02 ,  C07C67/333 ,  C07C67/347 ,  C07C67/475 ,  C07C67/56 ,  C07C69/533 ,  C07C69/58 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  C07D303/42 ,  C07C51/43

CPC classification number: C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

Abstract: Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,Ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,Ω-hydroxy acid or α,Ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,Ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,Ω-amino acid or α,Ω-amino ester, which may be (trans)esterified to form an α,Ωpolyester polyamine.

Abstract translation: 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原反应加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US06288188B1

公开(公告)日：2001-09-11

申请号：US09281838

申请日：1999-03-31

Applicant: James P. Godschalx ,  Duane R. Romer ,  Zenon Lysenko ,  Michael E. Mills

Inventor： James P. Godschalx ,  Duane R. Romer ,  Zenon Lysenko ,  Michael E. Mills

IPC: C08F3800

CPC classification number: C08G61/10 ,  C08G2261/312

Abstract: An oligomer, uncured polymer or cured polymer comprising the reaction product of one or more polyfunctional compounds containing two or more cyclopentadienone groups and at least one polyfunctional compound containing two or more aromatic acetylene groups wherein at least some of the polyfunctional compounds contain three or more reactive groups. Such oligomers and uncured polymers may be cured to form cured polymers which are useful as dielectrics in the microelectronics industry, especially for dielectrics in integrated circuits.

Abstract translation: 包含含有两个或多个环戊二烯酮基团的一种或多种多官能化合物与至少一种含有两个或多个芳族乙炔基团的多官能化合物的反应产物的低聚物，未固化聚合物或固化聚合物，其中至少一些多官能化合物含有三个或更多个反应性 团体 这种低聚物和未固化的聚合物可以固化以形成固化聚合物，其可用作微电子工业中的电介质，特别是用于集成电路中的电介质。

公开(公告)号：US5736748A

公开(公告)日：1998-04-07

申请号：US677749

申请日：1996-07-10

Applicant: Zenon Lysenko ,  Ritchie A. Wessling

Inventor： Zenon Lysenko ,  Ritchie A. Wessling

IPC: C08G65/32 ,  C08G18/48 ,  C08G18/50 ,  C08G63/668 ,  C08G63/685 ,  C08G65/333 ,  C09K3/08

CPC classification number: C08G18/5057 ,  C08G18/4866 ,  C08G63/668 ,  C08G63/6854 ,  C08G65/33365 ,  C08G65/33396

Abstract: The unsaturation of a hydroxyl-containing compound can be reduced by reaction with a nitrile oxide compound such as tetramethyl terephthalonitrile, N,N'-dioxide. The reaction of a nitrile oxide with terminal unsaturation associated with the preparation of a polyol from propylene oxide reduces the monol content of the polyol composition.

Abstract translation: 含羟基化合物的不饱和度可以通过与腈化合物如四甲基对苯二腈，N，N'-二氧化物的反应来还原。 与由环氧丙烷制备多元醇相关的腈氧化物与末端不饱和键的反应降低了多元醇组合物的单醇含量。

公开(公告)号：US5210171A

公开(公告)日：1993-05-11

申请号：US546597

申请日：1990-06-29

Applicant: William J. Harris ,  Zenon Lysenko ,  Carl W. Hurtig

Inventor： William J. Harris ,  Zenon Lysenko ,  Carl W. Hurtig

IPC: C07C227/06 ,  C08G73/22

CPC classification number: C08G73/22 ,  C07C227/06

Abstract: AB-polybenzoxazole monomer, such as 3-amino-4-hydroxybenzoic acid, can be synthesized in high yields from a hydroxy-benzoic acid or related compound in a three-step process of (1) nitration, (2) hydrolysis of the ester, and (3) reduction of the nitro moiety. The monomer is conveniently recovered as a phosphate salt in high purity by precipitating and recrystallizing from a phosphoric acid solution. The monomer may be polymerized in high concentrations in polyphosphoric acid containing high levels of P.sub.2 O.sub.5 to yield a high molecular weight polymer without dehydrohalogenation.

Abstract translation: 可以在（1）硝化的三步法中，从羟基 - 苯甲酸或相关化合物以高产率合成AB-聚苯并恶唑单体，例如3-氨基-4-羟基苯甲酸，（2）酯的水解 ，和（3）还原硝基部分。 通过从磷酸溶液中沉淀和重结晶，可以方便地将单体作为高纯度的磷酸盐回收。 单体可以在含有高含量的P 2 O 5的多磷酸中以高浓度聚合，得到高分子量聚合物，而无需脱卤化氢。

公开(公告)号：US4624758A

公开(公告)日：1986-11-25

申请号：US816502

申请日：1986-01-06

Applicant: Zenon Lysenko ,  Eric E. Bancroft

Inventor： Zenon Lysenko ,  Eric E. Bancroft

IPC: C25B3/02 ,  C07B29/06 ,  C07C49/64

CPC classification number: C25B3/02

Abstract: A method for producing dihydroxybenzophenones by the electrocatalytic oxidation of bis(4-hydroxyphenyl) methanes, or the quinone methide intermediate, with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ). Spent oxidant, in the form of DDQH.sub.2, may be recycled and electrochemically regenerated to active DDQ oxidant.

Abstract translation: 通过双（4-羟基苯基）甲烷或醌甲基化物中间体与2,3-二氯-5,6-二氰基-1,4-苯醌（DDQ）的电催化氧化制备二羟基二苯甲酮的方法。 以DDQH2形式的废氧化剂可以循环使用并电化学再生成活性DDQ氧化剂。

公开(公告)号：US08133930B2

公开(公告)日：2012-03-13

申请号：US10554633

申请日：2004-04-23

Applicant: Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

Inventor： Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

IPC: C08G18/28

CPC classification number: C08G18/4288 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4244 ,  C08G18/632 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

Abstract: Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The polyester is prepared in a multi-step process from animal or vegetable fats, by recovering the constitutent fatty acids, hydroformylating carbon-carbon double bonds in the fatty acids and reducing to form hydroxymethyl groups, and then forming a polyester by reaction with an initiator compound.

Abstract translation: 柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。 高当量多元醇的至少一部分是含有羟甲基的聚酯。 通过回收组分脂肪酸，在脂肪酸中加氢甲酰化碳 - 碳双键并还原形成羟甲基，然后通过与引发剂反应形成聚酯，从动物或植物脂肪的多步法制备聚酯 复合。

公开(公告)号：US08124812B2

公开(公告)日：2012-02-28

申请号：US12565446

申请日：2009-09-23

Applicant: Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

Inventor： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC: C07C47/02 ,  C07C45/50 ,  C07C29/14 ,  C07C59/147

CPC classification number: C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

Abstract: An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

Abstract translation: 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。