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    Catalyst comprising Ir or Ir and Ru for hydrazine decomposition
    1.
    发明授权
    Catalyst comprising Ir or Ir and Ru for hydrazine decomposition 失效
    包含Ir或Ir和Ru用于肼分解的催化剂

    公开(公告)号：US4124538A

    公开(公告)日：1978-11-07

    申请号：US371879

    申请日：1964-05-28

    Applicant: Warren E. Armstrong ,  Lloyd B. Ryland ,  Hervey H. Voge

    Inventor： Warren E. Armstrong ,  Lloyd B. Ryland ,  Hervey H. Voge

    IPC: B01J23/46 ,  C06D5/04 ,  B01J11/08

    CPC classification number: C06D5/04 ,  B01J23/468

    Abstract: 1. A catalyst for hydrazine decomposition consisting essentially of a carrier having a pore volume of at least 0.1 cubic centimeters per gram and a specific surface area, measured in square meters per gram, equal to 195 (C.sub.p + 0.013 + 0.736 V.sub.p) where C.sub.p is the specific heat capacity of the carrier at about 25.degree. C in calories per gram per degree and V.sub.p is the pore volume of the carrier in cubic centimeters per gram and metal of the group consisting of iridium, and mixtures consisting of iridium and ruthenium deposited on said carrier in an amount between 20% and about 40% by weight of the catalyst and distributed through the pores thereof in discrete particles sufficiently separated from each other so that they do not sinter or fuse together when the catalyst is at hydrazine decomposition temperature.

    Abstract translation: 1.一种用于肼分解的催化剂，其基本上由具有至少0.1立方厘米每克的孔体积和比表面积（以平方米/克计）等于195（Cp + 0.013 + 0.736Vp）的载体组成，其中Cp 是载体在约25℃下的比热容，每克/卡的热量，Vp是载体的孔体积，以立方厘米每克为单位，金属由铱组成，铱和钌组成的混合物沉积 在载体上的量为催化剂的20重量％至40重量％，并通过其分散的颗粒分散在彼此充分分离的颗粒中，使得当催化剂处于肼分解温度时，它们不会烧结或熔合在一起。

    Hydrocarbon conversion with an acidic multimetallic catalytic composite
    2.
    发明授权
    Hydrocarbon conversion with an acidic multimetallic catalytic composite 失效
    用酸性多金属催化复合材料进行烃转化

    公开(公告)号：US3998724A

    公开(公告)日：1976-12-21

    申请号：US576924

    申请日：1975-05-12

    Applicant: John C. Hayes

    Inventor： John C. Hayes

    IPC: B01J23/89 ,  C10G35/09 ,  B01J11/08 ,  C07C5/28 ,  C10G13/02

    CPC classification number: B01J23/89 ,  B01J23/8966 ,  C10G35/09 ,  Y10S585/94

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, an iron component, a cobalt or nickel component, and a halogen component with a porous carrier material. The platinum group component, iron component, cobalt or nickel component, and halogen component are present in the multimetallic catalyst in amount respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.1 to about 5 wt. % iron, about 0.1 to about 5 wt. % cobalt or nickel, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are relatively uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group component is present therein in the elemental metallic state, substantially all of the catalytically available cobalt or nickel component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states, while substantially all of the iron component is present therein in an oxidation state above that of the elemental metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

    Abstract translation: 通过在碳氢化合物转化条件下与含有催化有效量的铂族组分，铁组分，钴或镍组分和卤素组分与多孔载体材料的组合的酸性多金属催化复合物接触来转化碳氢化合物。 铂族组分，铁组分，钴或镍组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2wt。 ％铂族金属，约0.1至约5wt。 ％铁，约0.1至约5wt。 ％的钴或镍，以及约0.1至约3.5wt。 ％卤素。 此外，这些金属组分在仔细控制的氧化状态下相对均匀地分散在整个多孔载体材料中，使得基本上所有的铂族组分都存在于元素金属状态中，基本上所有的催化可用的钴或镍组分存在于 元素金属状态或在烃转化条件下或这些状态的混合物中可还原成元素金属状态的状态，而基本上所有的铁成分都存在于比元素金属高的氧化态。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

    Multimetallic catalysts
    3.
    发明授权
    Multimetallic catalysts 失效
    多元催化剂

    公开(公告)号：US3901827A

    公开(公告)日：1975-08-26

    申请号：US29276772

    申请日：1972-09-27

    Applicant: EXXON RESEARCH ENGINEERING CO

    Inventor： SINFELT JOHN H ,  CUSUMANO JAMES A

    IPC: B01J23/46 ,  B01J23/52 ,  B01J23/89 ,  B01J37/00 ,  C10G35/06 ,  C10G35/09 ,  B01J11/08 ,  B01J11/12 ,  B01J11/20

    CPC classification number: B01J23/892 ,  B01J23/46 ,  B01J23/52 ,  B01J23/8926 ,  B01J37/00 ,  C10G35/06 ,  C10G35/09

    Abstract: This invention relates to a process for preparing catalysts comprising two or more immiscible metals, said process comprising the step of incorporating an additional metal into said catalyst, said additional metal being characterized as being highly miscible with each of said immiscible metals whereby a catalyst is formed, wherein each metal is more miscible in the total metal mixture. In one preferred embodiment, this invention relates to a method for preparing multimetallic reforming catalysts wherein said metals are supported on a refractory oxide support. Catalysts prepared by the instant method are characterized as having increased stability due to the mutual miscibility of all the metals in the catalyst. In a specific embodiment, Group VIII - Group IB metal pairs having low miscibility, and which form useful bimetallic reforming catalysts because of the ability of Group IB metals to selectively inhibit the hydrogenolysis properties of Group VIII metals, are rendered more stable by the addition of a different Group VIII metal which acts to solubilize the first Group VIII metal and the Group IB metal in the total metal mixture. A specific improved catalyst results from the addition of nickel to a ruthenium-copper system; nickel acts to make the ruthenium and copper miscible in the total mixture. Similar results are found for Ru-Pt-Cu, platinum being the stabilizing Group VIII metal. Various catalysts prepared by the process of the instant invention are novel compositions of matter.

    Gas analyzer resistance element
    4.
    发明授权
    Gas analyzer resistance element 失效
    气体分析仪电阻元件

    公开(公告)号：US3883307A

    公开(公告)日：1975-05-13

    申请号：US42603573

    申请日：1973-12-19

    Applicant: AMBAC IND

    Inventor： KIM YOUNG HO

    IPC: B01J35/02 ,  G01N27/16 ,  B01J11/08 ,  G01N31/12

    CPC classification number: B01J35/02 ,  G01N27/16

    Abstract: A catalytic resistance element for use in a gas analyzer has an outer layer formed of particles of a metallic oxide, such as beryllium or aluminum, of about one micron average size, the outer layer preferably being of from about 100 to about 500 microns in thickness. The oxide particles have catalytic coatings formed by mixing the particles with a solution of a compound which is decomposed by heating to coat the particles with the catalyst and heating the mixture to cause such decomposition and coating. The outer layer is applied by mixing the oxide particles with binder solution, and applying drops of the mixture to the resistance element.

    Abstract translation: 用于气体分析仪的催化电阻元件具有由平均尺寸约一微米的金属氧化物（例如铍或铝）的颗粒形成的外层，外层的厚度优选为约100至约500微米 。 氧化物颗粒具有通过将颗粒与通过加热分解的化合物的溶液混合形成的催化涂层，以用催化剂涂覆颗粒并加热混合物以引起这种分解和涂覆。 通过将氧化物颗粒与粘合剂溶液混合并将混合物的液滴施加到电阻元件来施加外层。

    Nickel-free, all metal, catalyst element
    7.
    发明授权
    Nickel-free, all metal, catalyst element 失效
    无镍，所有金属，催化元素

    公开(公告)号：US3867313A

    公开(公告)日：1975-02-18

    申请号：US30295572

    申请日：1972-11-01

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： BREWER GERALD L

    IPC: B01D53/34 ,  B01D53/86 ,  B01J23/42 ,  B01J23/44 ,  B01J23/89 ,  B01J32/00 ,  B01J37/34 ,  B01J11/06 ,  B01J11/08

    CPC classification number: B01J23/42 ,  B01D53/34 ,  B01D53/86 ,  B01J23/44 ,  B01J23/8993 ,  B01J32/00 ,  B01J37/34

    Abstract: An all metal, high temperature resistant, catalyst element is provided by plating or depositing a noble metal comprising platinum and/or palladium onto a base material which comprises primarily aluminum, chromium and iron. The nickel-free, aluminum containing base material appears to be of advantage for at least certain all metal catalyst element operations and also results in substantially lower first cost catalyst units.

    Abstract translation: 通过将包含铂和/或钯的贵金属镀覆或沉积到主要包括铝，铬和铁的基材上来提供全金属，耐高温的催化剂元件。 对于至少某些所有金属催化剂元件操作来说，含有无镍的基体材料似乎是有利的，并且还导致基本上较低的第一成本的催化剂单元。

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