Method of utilizing humic acid to prepare layered humic acid/manganese oxide composite catalyst and its method of use thereof

    公开(公告)号:US12285747B2

    公开(公告)日:2025-04-29

    申请号:US18459263

    申请日:2023-08-31

    Abstract: A method of utilizing humic acid to prepare layered humic acid/manganese oxide composite catalyst and its application, the method includes the steps of: adding sodium hypochlorite, manganese salt and humic acid to a water source, stirring and mixing; then introducing into a filter device having a filter material of manganese and a support medium, and generating a layered humic acid/manganese oxide composite catalyst on a surface of the filter material while directing a continuous water flow of the water source into the filter device with a short empty bed contact time for a short time. The catalyst can be used to effectively remove manganese to maintain an effluent with a Mn2+ concentration of not more than 20 μg/L and to effectively remove heavy metals such as iron, manganese, arsenic, thallium, molybdenum or lead from the water source under neutral, acidic or alkaline conditions with a removal rate of 95% more.

    MULTILAYER CATALYTIC BED FOR THE PRODUCTION OF PHTHALIC ANHYDRIDE

    公开(公告)号:US20250128246A1

    公开(公告)日:2025-04-24

    申请号:US18682663

    申请日:2022-07-05

    Applicant: POLYNT S.P.A.

    Abstract: The present invention relates to a catalytic bed for the production of phthalic anhydride by oxidation of o-xylene and/or naphthalene. The catalytic bed comprises at least four layers of vanadium and titanium mixed oxide (VTiO) catalyst, arranged in series with respect to the flow of a gaseous feed mixture comprising o-xylene and/or naphthalene and an oxygen-containing gas, where the chemical composition and the height of the four layers of catalyst are optimized to improve the catalytic performance and their lifetime. The present invention also relates to a process for the production of phthalic anhydride by oxidation of o-xylene and/or naphthalene, which uses the above catalytic bed.

    FERRITE/SILVER/ZINC INDIUM SULFIDE COMPOSITE PHOTOCATALYST

    公开(公告)号:US20250099945A1

    公开(公告)日:2025-03-27

    申请号:US18731307

    申请日:2024-06-02

    Abstract: Preparation method of a lanthanum ferrite/silver/zinc indium sulfide composite photocatalyst. Includes following steps: dissolving citric acid, an iron-containing compound, and a lanthanum-containing compound in a first dispersant to obtain a first solution; carrying out a hydrothermal reaction on the first solution, prior to washing and drying sequentially, to obtain a first dried sample; calcining the first dried sample to obtain a lanthanum ferrite sample; adding deionized water and a silver nitrate solution in the lanthanum ferrite sample, prior to irradiation under a xenon lamp, and then washing and drying, to obtain a second dried sample; dissolving the second dried sample, zinc chloride, thioacetamide, and indium chloride in a second dispersant to obtain a second solution; and carrying out a hydrothermal reaction on the second solution, prior to washing and drying sequentially to obtain a lanthanum ferrite/silver/zinc indium sulfide composite photocatalyst, which can increase an absorption rate of visible light.

    Enhancement of the DeNOx SCR Performances of Vanadium-Based SCR Catalysts by Using Washcoats With Different Vanadium Contents

    公开(公告)号:US20250041801A1

    公开(公告)日:2025-02-06

    申请号:US18633716

    申请日:2024-04-12

    Abstract: The present invention discloses emissions treatment systems for the removal of NOx from exhaust combustion gases comprising, in the following order, from upstream to downstream: a) means for the injection of ammonia or an ammonia precursor solution into the exhaust gas stream, and b) a catalytic device comprising at least one carrier substrate, a material zone A comprising a first V/TiO2 SCR catalytically active composition SCRfirst which comprises at least one oxide of vanadium supported on titanium dioxide, a material zone B comprising a second V/TiO2 SCR catalytically active composition SCRsecond which comprises at least one oxide of vanadium supported on titanium dioxide, wherein the two material zones are affixed to the at least one carrier substrate in such a way that the exhaust gas first comes into contact with material zone A and then with material zone B, and wherein the ratio Vfirst:Vsecond of the percentages of vanadium contained in the first to the second V/TiO2 SCR catalytically active composition, each calculated as V2O5, is from 0.05 to 0.75. Methods for the removal of NOx emissions from exhaust gases of internal combustion engines are also envisaged.

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