TETRAHYDROFURAN PURGE TREATMENT PROCESS
    101.
    发明申请
    TETRAHYDROFURAN PURGE TREATMENT PROCESS 审中-公开
    四氯化碳净化处理工艺

    公开(公告)号:WO2014007930A1

    公开(公告)日:2014-01-09

    申请号:PCT/US2013/044033

    申请日:2013-06-04

    CPC classification number: C08G65/30 B01D3/36 C08G65/20 C08J11/02

    Abstract: The present invention provides a tetrahydrofuran purge stream treatment process, and a process for manufacturing polyether glycol comprising same. The process for treating a tetrahydrofuran stream purged from a polyether glycol manufacturing process comprises steps of neutralizing acidic substances in a tetrahydrofuran stream purged from the polyether glycol manufacturing process with an aqueous base solution, feeding the neutralized effluent to an azeotropic distillation column, and distilling tetrahydrofuran and water overhead from the azeotropic distillation column. The process can further comprise a step of disposing of the neutralized salts and excess base in the aqueous bottoms stream from the azeotropic distillation column. The process can further comprise steps of recovering THF from the overhead of the azeotropic distillation column, and recycling the recovered THF to a polyether glycol manufacturing process.

    Abstract translation: 本发明提供了一种四氢呋喃清洗流处理方法及其制备包含其的聚醚二醇的方法。 用于处理从聚醚二醇制造方法清洗的四氢呋喃流的方法包括以下步骤:用碱水溶液中和从聚醚二醇制造过程中清除的四氢呋喃流中的酸性物质,将中和的流出物进料到共沸蒸馏塔,并蒸馏四氢呋喃 和来自共沸蒸馏塔的塔顶馏出物。 该方法还可以包括在来自共沸蒸馏塔的水性塔底物流中处理中和的盐和过量的碱的步骤。 该方法还可以包括从共沸蒸馏塔的塔顶馏出物回收THF并将回收的THF循环到聚醚二醇制造方法的步骤。

    STABLE LIGAND MIXTURES AND PROCESSES FOR MAKING SAME
    102.
    发明申请
    STABLE LIGAND MIXTURES AND PROCESSES FOR MAKING SAME 审中-公开
    稳定的配体混合物和制备方法

    公开(公告)号:WO2013181095A1

    公开(公告)日:2013-12-05

    申请号:PCT/US2013/042631

    申请日:2013-05-24

    Abstract: A process of stabilizing a bidentate or tridentate phosphorus-based phosphite ester ligand or mixture thereof in a hydrocyanation reaction milieu comprising water, wherein the ligand or ligand mixture comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R 12 -X 12 ) (R 13 -X 13 ) P-X 14 -Y-Χ 24 -P (X 22 -R 22 ) (X 23 -R 23 ) or (ii) a tridentate triphosphite ligand of formula (ΙIIΑ) (R 12 -X 12 ) (R 13 -X 13 ) Ρ-Χ 14 -Y-X 32 -P(X 34 -R 34 )-(X 33 -Y 2 -R 24 -P(X 23 -R 23 )-(X 22 -R 22 ) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene group, comprising admixing the bidentate and/or tridentate with a stabilizing amount of one or more monodentate phosphite ligand of formula P(X 1 -R 1 )(X 2 -R 2 )(X 3 -R 3 ) where each X is oxygen or a bond, wherein the monodentate ligand has a rate of hydrolysis greater than the rate of hydrolysis of the bidentate or tridentate ligand in the presence of water in a hydrocyanation reaction milieu, and thereby preserve concentrations and proportions of the bidentate and/or tridentate ligand(s) in the ligand blend.

    Abstract translation: 在包含水的氢化氰化反应环境中稳定二齿或三齿磷基亚磷酸酯配体或其混合物的方法,其中配体或配体混合物包含(i)式(III)的二齿二亚磷酸酯配体,( R12-X12)(R13-X13)P-X14-Y-Chi24-P(X22-R22)(X23-R23)或(ii)式(IotaIIAlpha)(R12-X12)(R13-X13)的三齿三亚磷酸酯配体 )Rho-Chi14-Y-X32-P(X34-R34) - (X33-Y2-R24-P(X23-R23) - (X22-R22)其中X为氧或键,各Y为任选取代的 C6-C20亚芳基,其包括将二齿和/或三齿与稳定量的一种或多种式P(X1-R1)(X2-R2)(X3-R3)的单齿亚磷酸酯配体(X-R 3)混合,其中每个X是氧或 键,其中单齿配体的水解速率大于双氰胺或三齿配体在水解氰化反应环境中存在下的水解速率,从而保持浓度和 二配位体和/或三齿配体在配体共混物中的比例。

    REACTIVE CARRIERS FOR POLYMER MELT INJECTION
    105.
    发明申请
    REACTIVE CARRIERS FOR POLYMER MELT INJECTION 审中-公开
    聚合物熔体注射用反应载体

    公开(公告)号:WO2005076947A2

    公开(公告)日:2005-08-25

    申请号:PCT/US2005/003685

    申请日:2005-02-04

    Abstract: The present invention concerns a reactive carrier that forms no by-products during melt injection of polymer into articles such as sheets, films, fibers and containers. The reactive carrier is used to mix additives into the polymer resin. More particularly, the invention relates to the use of one or more cyclic anhydrides or substituted cyclic anhydrides as the reactive carrier. The polymer can be polyester or polyamide. Suitable cyclic anhydrides are those with a melt point of less than the polyester or polyamide, preferably less than about 160 °C, and more preferably less than about 125 °C. Most preferable are cyclic anhydrides with a melt point less than about 100 °C and especially suitable are those that are liquid at room temperature (25 °C). The cyclic anhydride may be selected from the group of succinic anhydride, substituted succinic anhydride, glutaric anhydride, substituted glutaric anhydride, phthalic anhydride, substituted phthalic anhydride, maleic anhydride, substituted maleic anhydride, or mixtures of two or more of these.

    Abstract translation: 本发明涉及在将聚合物熔融注射到诸如片材,薄膜,纤维和容器的制品中时不形成副产物的反应性载体。 反应性载体用于将添加剂混合到聚合物树脂中。 更具体地说,本发明涉及一种或多种环状酸酐或取代的环状酸酐作为反应性载体的用途。 聚合物可以是聚酯或聚酰胺。 合适的环状酸酐是熔点小于聚酯或聚酰胺的环状酸酐,优选小于约160℃,更优选小于约125℃。 最优选的是熔点小于约100℃的环状酸酐,特别适合在室温(25℃)下为液体的那些。 环状酸酐可以选自琥珀酸酐,取代的琥珀酸酐,戊二酸酐,取代的戊二酸酐,邻苯二甲酸酐,取代的邻苯二甲酸酐,马来酸酐,取代的马来酸酐,或它们中的两种或更多种的混合物。

    DEVICE FOR SURFACE COVERING
    109.
    发明申请

    公开(公告)号:WO2020188458A1

    公开(公告)日:2020-09-24

    申请号:PCT/IB2020/052358

    申请日:2020-03-16

    Abstract: A device includes a substrate (20), a first adhesive (33), and a carrier layer (50). The substrate has a finish layer (40). The substrate has sufficient flexibility to allow manual rolling and to allow manual unrolling without damage. The substrate has a plurality of discontinuous segments (70A, 70B, 70C). The first adhesive is disposed on an opposing side of the finish layer. The first adhesive is configured for pressure sensitive bonding. The first adhesive has a release characteristic such that the substrate can be bonded and disbonded relative to a substantially planar surface and incur no damage. The carrier layer (50) is bonded to the finish layer by a second adhesive (55). The second adhesive is configured to retain the plurality of discontinuous segments in fixed spatial alignment. The second adhesive is configured to cleanly disbond from the finish layer by manual peeling.

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