Invention Grant
- Patent Title: Continuous hydrogenation of levulinic acid
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Application No.: US15551133Application Date: 2016-02-16
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Publication No.: US10144718B2Publication Date: 2018-12-04
- Inventor: Barthel Engendahl , Roel Wim Wiertz , Jan Van Der Spoel
- Applicant: DSM IP ASSETS B.V.
- Applicant Address: NL Heerlen
- Assignee: DSM IP ASSETS B.V.
- Current Assignee: DSM IP ASSETS B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP15155585.1 20150218
- International Application: PCT/EP2016/053254 WO 20160216
- International Announcement: WO2016/131821 WO 20160825
- Main IPC: C07D307/33
- IPC: C07D307/33 ; B01J21/18 ; B01J21/06 ; B01J23/46 ; B01J35/00

Abstract:
The invention relates to a continuous or repetitive batch process for the hydrogenation of levulinic acid (LA) or esters thereof to at least gamma valerolactone (GVL) in a reactor comprising a feed stream and an outlet stream, in the presence of a solid Ru catalyst, said process comprising (a) pretreating said solid Ru catalyst with a reductant; and (b) reacting levulinic acid with hydrogen and the pretreated solid Ru catalyst obtained in step (a) at a temperature and residence time suitable to form at least GVL, characterized in that the pretreatment is in the presence of a first solvent which comprises water. This process is stable and little or no Ru will leak form the support.
Public/Granted literature
- US20180022721A1 CONTINUOUS HYDROGENATION OF LEVULINIC ACID Public/Granted day:2018-01-25
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