Invention Grant
- Patent Title: Methanation reaction catalyst, method for producing methanation reaction catalyst and method for producing methane
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Application No.: US15326959Application Date: 2015-07-16
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Publication No.: US10343147B2Publication Date: 2019-07-09
- Inventor: Koji Hashimoto , Hiroyuki Takano , Kouichi Izumiya , Naokazu Kumagai
- Applicant: HITACHI ZOSEN CORPORATION
- Applicant Address: JP Osaka
- Assignee: HITACHI ZOSEN CORPORATION
- Current Assignee: HITACHI ZOSEN CORPORATION
- Current Assignee Address: JP Osaka
- Agency: Edwards Neils, LLC
- Agent Jean C. Edwards, Esq.
- Priority: JP2014-148373 20140719
- International Application: PCT/JP2015/070437 WO 20150716
- International Announcement: WO2016/013488 WO 20160128
- Main IPC: C07C1/12
- IPC: C07C1/12 ; C07C9/04 ; B01J23/755 ; B01J37/16 ; B01J23/78 ; B01J23/02 ; B01J35/00 ; B01J37/04 ; B01J37/08 ; B01J37/18 ; B01J23/00 ; C07B61/00 ; B01J35/02 ; B01J37/00

Abstract:
A methanation reaction catalyst for methanation by allowing carbon dioxide to react with hydrogen, wherein the methanation reaction catalyst includes a stabilized zirconia support having a tetragonal crystal structure and in which Ca and Ni are incorporated in the crystal structure, and Ni in the metal state supported on the stabilized zirconia support, includes the following in atomic % based on metals in the element state, A) Zr composing the stabilized zirconia support: 6 to 62 atomic %, B) Ca incorporated in the crystal structure: 1 to 20 atomic %, and C) a total of Ni incorporated in the crystal structure and Ni supported on the stabilized zirconia support: 30 to 90 atomic %, and the atomic ratio of Ca/(Zr+Ca) is 0.14 to 0.25.
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