To provide a laminate having characteristics of a fluorinated polymer film such as weather resistance and stain resistance, and having an increased solar reflectance by a light reflection layer, wherein the solar reflectance is less likely to decrease over a long period of time, and the light reflection layer is less likely to delaminate; and a production process thereof.A laminate 1 comprising a substrate 10 containing a first fluorinated polymer, a light reflection layer 12 made of a non-curable resin composition containing a second fluorinated polymer and an aluminum pigment, and a protective layer 14 obtained by curing a curable resin composition containing a third fluorinated polymer having a crosslinkable group and a curing agent for curing the third fluorinated polymer, wherein the light reflection layer 12 is disposed between the substrate 10 and the protective layer 14, the light reflection layer 12 has a thickness of from 0.5 to 5 μm, and the protective layer 14 has a thickness of from 0.3 to 2 μm.