A method of fabricating a liquid crystal display device includes forming a first alignment layer on a first substrate, forming a second alignment layer on a second substrate, disposing the first substrate and the second substrate such that the first alignment layer and the second alignment layer are spaced apart, forming a liquid crystal layer including liquid crystal molecules between the first alignment layer and the second alignment layer and forming an electrode layer on one of the first substrate and the second substrate, the electrode layer applying an electric field to the liquid crystal molecules along a direction parallel to the first and second substrates, the forming the first alignment layer including applying a copolymer solution including first moieties and second moieties, and the first moieties have affinity with the first substrate, and the second moieties have compatibility with the liquid crystal molecules and heating the first alignment layer.