Invention Grant
- Patent Title: Oxidative desulfurization of liquid fuels using metal sulfide quantum dots/graphen oxid hybrid nanocatalyst
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Application No.: US16288114Application Date: 2019-02-28
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Publication No.: US10689584B2Publication Date: 2020-06-23
- Inventor: Zohal Safaei Mahmoudabadi , Alimorad Rashidi , Ahmad Tavasoli , Mansour Bazmi , Hajjar Farshidi
- Applicant: Zohal Safaei Mahmoudabadi , Alimorad Rashidi , Ahmad Tavasoli , Mansour Bazmi , Hajjar Farshidi
- Agency: Bajwa IP Law Firm
- Agent Haris Zaheer Bajwa
- Main IPC: C10G53/14
- IPC: C10G53/14 ; C10G27/14 ; B01J27/051 ; B01J35/00 ; B01J21/18 ; B01J37/04 ; B01J37/34 ; B01J37/00 ; B01J37/02 ; B01J27/043 ; B01J27/047

Abstract:
A method for oxidative desulfurization of liquid hydrocarbon fuels is disclosed. The method includes contacting a liquid fuel with a quantum dot hybrid catalyst including metal sulfide quantum dots intercalated over graphene oxide layers in a reactor vessel, heating the reactor vessel to a temperature between 25° C. and 200° C., and reducing sulfur content of the liquid fuel with a sulfur reduction amount of more than 95% wt. Reducing the sulfur content of the liquid fuel with the sulfur reduction amount of more than 95% wt. includes producing sulfone and sulfoxide compounds by oxidizing the liquid fuel with ozone gas in the presence of the quantum dot hybrid catalyst at the temperature between 25° C. and 200° C., and separating the sulfone and sulfoxide compounds from the liquid fuel by extracting the sulfone and sulfoxide with an extraction solvent.
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