The present invention relates to a nanoparticle composition having antibacterial and exothermic properties and a manufacturing method thereof, more particularly, a nanoparticle composition with very good antibacterial and exothermic properties obtained by preparing an ionized calcium powder from shells obtained through foreign matter removing, cleaning, drying, sintering, cooling and pulverizing processes, and passing it through a tourmaline mixing stage, a surfactant treatment stage, a synthetic resin mixing stage and a nanoparticle molding stage, and a manufacturing method thereof.