A method and apparatus for fabricating multifunction membranes comprising cross-aligned nanofiber in an electrospinning device, the method comprising providing a multiple segment collector including at least a first segment, a second segment, and an intermediate segment to collectively present an elongated cylindrical structure; electrically charging an edge conductor circumferentially resident on the first segment and on the second segment; rotating the elongated cylindrical structure on a drive unit around a longitudinal axis; the elongated cylindrical structure holding electrospun fiber substantially aligned with the longitudinal axis when the edge conductors are excited with a charge of opposite polarity relative to charged fiber, and attracting electrospun fiber on to its surface around the longitudinal axis at least when the edge conductors are absent a charge or grounded and a charged electrode is positioned opposite a fiber emitter; and repeating the process multiple times to form layers of nanofibers encapsulating agents of interest.