Methods for forming a fluoropolymer coated component, such as a metal component, comprise applying an adhesion promoter onto a surface of the component; applying an organic material onto the adhesion promoter; and applying a mixture comprising a fluoropolymer and a solvent selected from a furan or a fluorinated solvent onto the organic material. Fluoropolymer coatings have a thickness of from about 5 mil to about 80 mil on a component, an average porosity of from about 20% to about 70% based on the total volume of the layer, and a void density of from about 1011 to about 1013 voids per cm3.