An embodiment of the present invention provides: an adhesive coating composition capable of attaching (coupling) an electrical steel sheet without using an existing coupling method, such as welding, clamping, or interlocking; an electrical steel sheet laminate employing the same; and a manufacturing method therefor. The adhesive coating composition according to an embodiment of the present invention comprises: 40-95 wt % of a first component comprising an organic/inorganic composite in which inorganic nanoparticles are substituted in a water-soluble resin; 1-50 wt % of a second component comprising a composite metal phosphate; and 1-10 wt % of an additive.