A ceramic honeycomb structure includes: an outer peripheral wall; and a partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the plurality of cells to form a fluid flow path extending from one end face to other end face. The honeycomb structure contains: 1) particles including one or more selected from silicon carbide, silicon nitride and aluminum nitride; and 2) silicon doped with a dopant. The dopant is a Group 13 element or a Group 15 element. The honeycomb structure has a silicon content (B) of from 20 to 80% by mass, and the honeycomb structure has a porosity of 30% or less.