Invention Grant
US07666506B2 Surface-modified metal oxides prepared by precipitation in the presence of a copolymer having N-vinylamide units, production processes and use thereof in cosmetic preparations 失效
通过在具有N-乙烯基酰胺单元的共聚物存在下沉淀制备的表面改性金属氧化物,其制备方法及其在化妆品制剂中的用途

Surface-modified metal oxides prepared by precipitation in the presence of a copolymer having N-vinylamide units, production processes and use thereof in cosmetic preparations
Abstract:
The present invention relates to surface-modified nanoparticulate metal oxides where the metal is chosen from the group consisting of aluminum, cerium, iron, titanium, zinc and zirconium, wherein the surface modification comprises a coating with a copolymer P comprising, as monomers, A) 1 to 99 mol % of a N-vinylamide N-vinylpyrrolidone and B) 99 to 1 mol % of a monomer comprising, per molecule, a free-radically polymerizable α,β-ethylenically unsaturated double bond and an anionogenic and/or anionic group, with the proviso that the copolymer P must comprise no further monomers chosen from the group consisting of C8-C30-alkyl esters of monoethylenically unsaturated C3-C8-carboxylic acids, N-alkyl- or N,N-dialkyl-substituted amides of acrylic acid or of methacrylic acid with C8-C18-alkyl radicals, or vinyl esters of aliphatic C8-C30-carboxylic acids.
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