Flexible thermal control coatings for use on components of spacecraft and methods for fabricating such coatings are provided. In an exemplary embodiment, a flexible thermal control coating comprises a flexible organic binder for disposition on the component and an inorganic material having a radiation absorptance (α) of less than about 0.2 and an emissivity (ε) of at least about 0.6. The inorganic material and the organic binder are oriented relative to each other so that an exterior surface of the coating has a higher concentration of inorganic material than an interior surface of the coating and a lower concentration of organic binder than the interior surface.