Invention Grant
- Patent Title: Isobutene polymerisation in the presence of a donor and fluorinated acids complex
- Patent Title (中): 在供体和氟化酸络合物存在下,异丁烯聚合
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Application No.: US11597274Application Date: 2005-05-11
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Publication No.: US07932332B2Publication Date: 2011-04-26
- Inventor: Mirjam Herrlich-Loos , Christian Drohmann , Darijo Mijolovic , Thomas Wettling , Helmut Mach
- Applicant: Mirjam Herrlich-Loos , Christian Drohmann , Darijo Mijolovic , Thomas Wettling , Helmut Mach
- Applicant Address: DE Ludwigshafen
- Assignee: BASF Aktiengesellschaft
- Current Assignee: BASF Aktiengesellschaft
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP04011971 20040519
- International Application: PCT/EP2005/005093 WO 20050511
- International Announcement: WO2005/116094 WO 20051208
- Main IPC: C08F2/00
- IPC: C08F2/00

Abstract:
The invention relates to a method for producing mainly ethylenically unsaturated isobutene polymers, wherein the sum of proportions of molecules with a double bond in an α position and molecules with a double bond in a position β is increased to 75% mol by polymerising isobutene in a liquid phase in the presence of a diluted or dispersed catalyst complex which comprises (i) an electron donor and (ii) a compound of general formula (I) Ha Meb [MFx]c, wherein Me is a metal with oxidation state m, M is an element selected from elements of the groups 2, 3, 4, 5, 10, 11, 13, 14 or 15 of the periodic table according to the IUPAC notation of an element oxidation number n, a is an integer ≧1, b is an integer ≧0, x is an integer ≧2 and c is [(a+mb)/(x−n)]. The catalyst is preferably embodied in the form of HBF4 O(CH3)2. The inventive method makes it possible to obtain an isobutene polymer having a low fluorine-content even using technical C4 hydrocarbon portions as an isobutene source.
Public/Granted literature
- US20070225459A1 Isobutene Polymerisation in the Presence of a Donor and fluorinated Acids Complex Public/Granted day:2007-09-27
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