PREPARATION OF ISOBUTENE HOMO- OR COPOLYMER DERIVATIVES
    2.
    发明申请
    PREPARATION OF ISOBUTENE HOMO- OR COPOLYMER DERIVATIVES 有权
    ISOBUTENE共聚物衍生物的制备

    公开(公告)号:US20120142868A1

    公开(公告)日:2012-06-07

    申请号:US13305283

    申请日:2011-11-28

    Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.

    Abstract translation: (i)在卤化铁 - 给体络合物,三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法( ii)使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应,和(iii)在与亚结构反应的情况下,进一步反应以完成低分子量的形成 极地组。 均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团,硝基,羟基,硫醇基,羧酸或羧酸 衍生功能,磺酸或磺酸衍生物功能,醛官能团和/或甲硅烷基。

    METHOD FOR THE REMOVAL OF ISOBUTENE OLIGOMERS FROM AN ISOBUTENE POLYMER
    4.
    发明申请
    METHOD FOR THE REMOVAL OF ISOBUTENE OLIGOMERS FROM AN ISOBUTENE POLYMER 失效
    从ISOBUTENE聚合物中去除异构低聚物的方法

    公开(公告)号:US20100004427A1

    公开(公告)日:2010-01-07

    申请号:US12514899

    申请日:2007-11-13

    CPC classification number: C08F6/001 C08F6/04 C08L23/20

    Abstract: A process is described for removing isobutene oligomers from an isobutene polymer by stripping the isobutene polymer with vapors of a saturated hydrocarbon having at least 8 carbon atoms and at least partly driving out the isobutene oligomers. Troublesome isobutene oligomers are substantially removed without impairing the reactivity of the isobutene polymer (expressed as the content of the methylidene double bonds).

    Abstract translation: 描述了通过用具有至少8个碳原子的饱和烃的蒸气汽提异丁烯聚合物并且至少部分驱除异丁烯低聚物来从异丁烯聚合物中除去异丁烯低聚物的方法。 基本上除去麻烦的异丁烯低聚物,而不损害异丁烯聚合物的反应性(以亚甲基双键的含量表示)。

    Method for producing polyisobutene
    8.
    发明授权
    Method for producing polyisobutene 有权
    生产聚异丁烯的方法

    公开(公告)号:US07217773B2

    公开(公告)日:2007-05-15

    申请号:US10542928

    申请日:2004-01-23

    Abstract: A process is described for preparing polyisobutene having a content of terminal vinylidene groups of at least 75 mol % by polymerizing isobutene or isobutenic hydrocarbon mixtures in the liquid phase in the presence of a boron trifluoride complex catalyst of the composition (BF3)a.L1b.L2c.L3d where L1 is water, a primary C1–C5-alkanol and/or a secondary C3–C5-alkanol, L2 is at least one aldehyde and/or one ketone, L3 is an ether having at least 5 carbon atoms, a secondary alkanol having at least 6 carbon atoms, a primary alkanol having at least 6 carbon atoms and/or a tertiary alkanol, the b:a ratio is in the range from 0.9 to 3.0, the c:a ratio is in the range from 0.01 to 0.5, and the d:a ratio is in the range from 0 to 1.0.

    Abstract translation: 描述了一种制备具有至少75mol%的末端亚乙烯基含量的聚异丁烯的方法,通过在液相中聚合异丁烯或异丁烯烃混合物,在三元组配合物催化剂存在下, 描述=“在线公式”end =“lead”?>(BF 3) a β-in-line-formula description =“In-line-formula”=“In- 其中L 1是水,主要C 1 -C 5 - 烷醇和/或 仲C 3 -C 5 - 烷醇,L 2是至少一种醛和/或一种酮,L 3, SUP>是具有至少5个碳原子的醚,具有至少6个碳原子的仲链烷醇,具有至少6个碳原子的伯烷醇和/或叔链烷醇,b:a的比例在0.9至 3.0,c:a的比例在0.01至0.5的范围内,d:a的比例为 范围从0到1.0。

    Polyisobutenyl ethers and thioethers
    9.
    发明授权
    Polyisobutenyl ethers and thioethers 失效
    聚异丁烯基醚和硫醚

    公开(公告)号:US06958382B2

    公开(公告)日:2005-10-25

    申请号:US10698457

    申请日:2003-11-03

    CPC classification number: C08G81/021 C08F8/00 C08F110/10

    Abstract: A process for preparing polyisobutenyl (thio)ethers by reacting a polyisobutene epoxide having at least one terminal epoxide group with itself, with other epoxides and/or with nucleophiles selected from among alcohols and thiols in the presence of a Lewis-acid compound as catalyst and/or a cationic photoinitiator with illumination is described. The side reaction of the rearrangement of the epoxide to the polyisobutenyl aldehyde is suppressed. In addition, a curable composition comprising a polyisobutene epoxide, an epoxide different therefrom and optionally a poly(thi)ol is also described.

    Abstract translation: 通过使具有至少一个末端环氧基团的聚异丁烯环氧化物自身与其它环氧化物和/或与路易斯酸化合物作为催化剂存在下的选自醇和硫醇的亲核试剂反应来制备聚异丁烯基(硫代)醚的方法,以及 /或具有照明的阳离子光引发剂。 环氧化物与聚异丁烯醛的重排的副反应被抑制。 此外,还描述了包含聚异丁烯环氧化物,与其不同的环氧化物和任选的聚(硫醇)的可固化组合物。

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