A method to prepare a flexible and breathable protective glove having excellent grip in both aqueous and oil environments includes coating an electrolyte treated glove liner substrate with a non-foamed dispersion of a polymeric material. The resulting semi-gelled polymeric coating which partially penetrates the depth of the glove liner substrate, is treated with a foamed solution of a surfactant, tenside or aerosol solution and the foam treated coating is overcoated with an electrolyte solution. In a resulting chemical or physical reaction, fine pores and cavities are formed in and on the polymer coating.