A martensitic stainless steel, having high temper softening resistance, for disc brakes is provided. The martensitic stainless steel is not seriously softened by maintaining the steel at more than 600° C. The steel has a hardness of 32 or more or a hardness of 30 or more in HRC after the steel is tempered at 650° C. for one hour or tempered at 670° C. for one hour, respectively. In particular, the martensitic stainless steel for disc brakes contains less than 0.050 mass % carbon, 1.0 mass % or less silicon, 2.0 mass % or less manganese, 0.04 mass % or less phosphorus, 0.010 mass % or less sulfur, 0.2 mass % or less aluminum, more than 11.5 mass % to 15.0 mass % chromium, 0.5 mass % to 2.0 mass % nickel, more than 0.50 mass % to 4.0 mass %. copper, more than 0.08 mass % to 0.6 mass % niobium, and less than 0.09 mass % nitrogen, the remainder being iron and unavoidable impurities. The carbon content, the nitrogen content, the niobium content, the chromium content, the silicon content, the nickel content, the manganese content, and the copper content satisfy the following inequalities (1) and (2): 0.03≦[C]+[N]−13/93×[Nb]≦0.09   (1) 5×[Cr]+10×[Si]+30×[Nb]−9×[Ni]−5×[Mn]−3×[Cu]−225×[N]−270×[C]≦40   (2).