Invention Grant
- Patent Title: Methods for the synthesis of deuterated acrylate salts
- Patent Title (中): 氘代丙烯酸盐的合成方法
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Application No.: US13611927Application Date: 2012-09-12
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Publication No.: US08829238B2Publication Date: 2014-09-09
- Inventor: Jun Yang , Peter V. Bonnesen , Kunlun Hong
- Applicant: Jun Yang , Peter V. Bonnesen , Kunlun Hong
- Applicant Address: US TN Oak Ridge
- Assignee: UT-Battelle, LLC
- Current Assignee: UT-Battelle, LLC
- Current Assignee Address: US TN Oak Ridge
- Agency: Scully, Scott, Murphy & Presser, P.C.
- Main IPC: C07C51/36
- IPC: C07C51/36
Abstract:
A method for synthesizing a deuterated acrylate of the Formula (1), the method comprising: (i) deuterating a propiolate compound of Formula (2) to a methyne-deuterated propiolate compound of Formula (3) in the presence of a base and D2O: and (ii) reductively deuterating the methyne-deuterated propiolate compound of Formula (3) in a reaction solvent in the presence of deuterium gas and a palladium-containing catalyst to afford the deuterated acrylate of the Formula (1). The resulting deuterated acrylate compounds, derivatives thereof, and polymers derived therefrom are also described.
Public/Granted literature
- US20130079554A1 METHODS FOR THE SYNTHESIS OF DEUTERATED ACRYLATE SALTS Public/Granted day:2013-03-28
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