Invention Grant
- Patent Title: Process for preparing acrylic acid from methanol and acetic acid
- Patent Title (中): 从甲醇和乙酸制备丙烯酸的方法
-
Application No.: US13233560Application Date: 2011-09-15
-
Publication No.: US08877966B2Publication Date: 2014-11-04
- Inventor: Stefanie Herzog , Stefan Altwasser , Klaus Joachim Mueller-Engel
- Applicant: Stefanie Herzog , Stefan Altwasser , Klaus Joachim Mueller-Engel
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102010040921 20100916
- Main IPC: C07B35/00
- IPC: C07B35/00 ; B01J23/00 ; C07C57/04 ; B01J23/881 ; B01J35/00 ; C07C51/44 ; C07C51/353 ; B01J27/198 ; C07C45/38 ; B01J35/02 ; B01J37/00

Abstract:
A process for preparing acrylic acid from methanol and acetic acid, in which, in a reaction zone A, the methanol is partially oxidized to formaldehyde in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and an acetic acid source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed to acrylic acid under heterogeneous catalysis in a reaction zone B with acetic acid present in reaction gas input mixture B, and unconverted acetic acid still present alongside the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.
Public/Granted literature
- US20120071688A1 PROCESS FOR PREPARING ACRYLIC ACID FROM METHANOL AND ACETIC ACID Public/Granted day:2012-03-22
Information query