Invention Grant
- Patent Title: Process for adiabatic production of mononitrotoluene
- Patent Title (中): 绝热生产单硝基甲苯的方法
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Application No.: US13427688Application Date: 2012-03-22
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Publication No.: US08907144B2Publication Date: 2014-12-09
- Inventor: Michael Gattrell
- Applicant: Michael Gattrell
- Applicant Address: IE Dublin
- Assignee: NORAM International Limited
- Current Assignee: NORAM International Limited
- Current Assignee Address: IE Dublin
- Agency: Oyen Wiggs Green Mutala LLP
- Main IPC: C07C205/00
- IPC: C07C205/00 ; C07B41/00 ; C07C27/26

Abstract:
A process for continuous adiabatic nitration of toluene to mononitrotoluene (MNT). The process yields a product quality of MNT that is comparable to that obtained by isothermal production. The process uses excess toluene, with the reaction rate being controlled to maintain a residual of 0.003-0.102 wt % nitric acid in the spent acid and an orange to red color of the spent acid. Further process conditions include re-concentrated sulfuric acid at 83 to 99 degrees C. with a concentration of sulfuric acid from 66 to 70.5 wt %. This is mixed with nitric acid to generate a mixed acid with 1.0 to 3.8 wt % nitric acid and toluene is added at a rate of 1.1 to 1.71 moles toluene/mole nitric acid. The reactants are mixed in a reactor with an overall average mixing intensity of 5.8 to 19 W/kg of contained solution.
Public/Granted literature
- US20130253233A1 PROCESS FOR ADIABATIC PRODUCTION OF MONONITROTOLUENE Public/Granted day:2013-09-26
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