Invention Grant
- Patent Title: Method for producing ethylene glycol from oxalate through the fluidized bed catalytic reaction
- Patent Title (中): 通过流化床催化反应从草酸生产乙二醇的方法
-
Application No.: US14000876Application Date: 2012-02-24
-
Publication No.: US09102583B2Publication Date: 2015-08-11
- Inventor: Weimin Yang , Juntao Liu , Wanmin Wang , Jun Kuai
- Applicant: Weimin Yang , Juntao Liu , Wanmin Wang , Jun Kuai
- Applicant Address: CN Beijing CN Shanghai
- Assignee: CHINA PETROLEUM & CHEMICAL CORPORATION,SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
- Current Assignee: CHINA PETROLEUM & CHEMICAL CORPORATION,SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
- Current Assignee Address: CN Beijing CN Shanghai
- Agency: Buchanan Ingersoll & Rooney PC
- Priority: CN201110045356 20110225; CN201110045364 20110225
- International Application: PCT/CN2012/000236 WO 20120224
- International Announcement: WO2012/113267 WO 20120830
- Main IPC: C07C27/04
- IPC: C07C27/04 ; C07C29/149 ; B01J23/83 ; B01J23/84 ; B01J23/843 ; B01J23/888 ; B01J29/48

Abstract:
A process for producing ethylene glycol includes contacting an oxalate with a fluidized bed catalyst under the following conditions: a reaction temperature of from about 170 to about 270° C., a weight space velocity of oxalate of from about 0.2 to about 7 hours−1, a hydrogen/ester molar ratio of about 20˜200:1, a reaction pressure of from about 1.5 to about 10 MPa, and a reaction temperature difference T of from about 1 to about 15° C. The fluidized bed catalyst includes: a) from about 5 to about 80 parts by weight of copper and the oxide thereof, b) from about 10 to about 90 parts by weight of at least one carrier selected from silica, molecular sieve or alumina, c) from about 0.01 to about 30 parts by weight of bismuth and tungsten metallic elements or the oxides thereof, or cerium and niobium metallic elements or the oxides thereof.
Public/Granted literature
- US20130331617A1 METHOD FOR PRODUCING ETHYLENE GLYCOL FROM OXALATE THROUGH THE FLUIDIZED BED CATALYTIC REACTION Public/Granted day:2013-12-12
Information query