A highly optically clear, composite film has a predominantly thermoplastic polyester base layer of A/B/C-layered structure and a polyester and polyurethane blend primer layer Preferably core layer B of the base layer is substantially particle-free polyester and outer layers A and C include organic and/or inorganic particles. The primer layer is crosslinked using a carbodiimide crosslinking agent. The primer layer and base layer composite can be laminated with a protective layer of primarily acrylic polymer for a solar control film. Functional additives, such as UV light blockers can be present in layers of the composite and solar control films. The primer layer combination of polyurethane and crosslinking by carbodiimide, provides the acrylic coated polyester solar control film with notably reduced iridescence and durable adhesion between polyester and acrylic layers in moist and warm service conditions.