Invention Grant
US09206091B2 Processes and systems for synthesis gas conversion using a hybrid fischer-tropsch catalyst in a compact heat exchange reactor
有权
在紧凑型热交换反应器中使用混合费 - 托催化剂进行合成气转化的方法和系统
- Patent Title: Processes and systems for synthesis gas conversion using a hybrid fischer-tropsch catalyst in a compact heat exchange reactor
- Patent Title (中): 在紧凑型热交换反应器中使用混合费 - 托催化剂进行合成气转化的方法和系统
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Application No.: US14219774Application Date: 2014-03-19
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Publication No.: US09206091B2Publication Date: 2015-12-08
- Inventor: Robert James Saxton, Jr. , Kandaswamy Jothimurugesan , Charles Leonard Kibby
- Applicant: Robert James Saxton, Jr. , Kandaswamy Jothimurugesan , Charles Leonard Kibby
- Applicant Address: US CA San Ramon
- Assignee: Chevron U.S.A. Inc.
- Current Assignee: Chevron U.S.A. Inc.
- Current Assignee Address: US CA San Ramon
- Agent Karen R. DiDomenicis
- Main IPC: C07C27/00
- IPC: C07C27/00 ; C07C1/04 ; B01J19/00 ; B01J35/00 ; B01J8/00 ; B01J23/75 ; B01J23/89 ; B01J29/00 ; B01J35/02 ; B01J35/10 ; C10G2/00 ; F28F3/00 ; F28D9/00

Abstract:
Disclosed are a process and a system for synthesis gas conversion. The process includes contacting a synthesis gas feed of hydrogen and carbon monoxide having a H2/CO ratio from 0.5 to 3.0 with a hybrid catalyst of particles having a particle size from 50 to 500 μm and having at least one zeolite and a Fischer-Tropsch component wherein the ratio of zeolite to Fischer-Tropsch component is from 0.1:1 to 30:1 and the hybrid catalyst includes from 0.5 to 40 wt % Fischer-Tropsch component. The process is conducted in a compact heat exchange reactor having a set of reaction passages disposed between a synthesis gas feed header and a products header and a set of coolant passages disposed between a coolant inlet header and a coolant outlet header. The set of coolant passages conducts a coolant therethrough, and the set of reaction passages contains the hybrid catalyst therein and conducts synthesis gas and reaction products therethrough. The process is conducted at a temperature from 200 to 2800° C., a pressure from 5 to 40 atmospheres, a recycle ratio from 1 to 3, and a gaseous hourly space velocity less than 20,000 volumes of gas per volume of catalyst per hour. The effluent produced includes a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons and less than 5 wt % C21+ hydrocarbons at a C5+ productivity from 0.05 to 2 gC5+/gcat/h.
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