Invention Grant
- Patent Title: Method for producing acrylonitrile
- Patent Title (中): 制备丙烯腈的方法
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Application No.: US14381360Application Date: 2013-02-26
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Publication No.: US09328063B2Publication Date: 2016-05-03
- Inventor: Takashi Karasuda , Hirokazu Watanabe , Motoo Yanagita , Kazufumi Nishida
- Applicant: Mitsubishi Rayon Co., Ltd.
- Applicant Address: JP Chiyoda-ku
- Assignee: Mitsubishi Rayon Co., Ltd.
- Current Assignee: Mitsubishi Rayon Co., Ltd.
- Current Assignee Address: JP Chiyoda-ku
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P
- Priority: JP2012-042833 20120229
- International Application: PCT/JP2013/054944 WO 20130226
- International Announcement: WO2013/129385 WO 20130906
- Main IPC: C07C253/26
- IPC: C07C253/26 ; B01J27/057 ; B01J38/48 ; B01J35/00

Abstract:
The invention relates to a method for producing acrylonitrile which includes a vapor phase catalytic ammoxidation process of performing vapor phase catalytic ammoxidation by bringing a source gas containing propylene, molecular oxygen, and ammonia into contact with a fluidized bed catalyst to obtain acrylonitrile. The method is characterized in that the fluidized bed catalyst consists of particles containing Fe, Sb, and Te, and the vapor phase catalytic ammoxidation process is performed while maintaining a B/A in the range of 2.0 to 5.0, where A denotes an atomic ratio of Te/Sb in a bulk composition of the fluidized bed catalyst and B denotes an atomic ratio of Te/Sb in a surface composition of the particles of the fluidized bed catalyst. According to the method for producing acrylonitrile of the invention, it is possible to stably maintain a high acrylonitrile yield over a long period of time.
Public/Granted literature
- US20150031907A1 METHOD FOR PRODUCING ACRYLONITRILE Public/Granted day:2015-01-29
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