Invention Grant
US09534071B2 Process for the preparation of functionalized and branched elastomeric copolymers and use thereof in vulcanizable elastomeric compositions
有权
用于制备官能化和支化弹性体共聚物的方法及其在可硫化弹性体组合物中的用途
- Patent Title: Process for the preparation of functionalized and branched elastomeric copolymers and use thereof in vulcanizable elastomeric compositions
- Patent Title (中): 用于制备官能化和支化弹性体共聚物的方法及其在可硫化弹性体组合物中的用途
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Application No.: US14404703Application Date: 2013-06-10
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Publication No.: US09534071B2Publication Date: 2017-01-03
- Inventor: Luca Soddu
- Applicant: Versalis S.P.A.
- Applicant Address: IT
- Assignee: VERSALIS S.P.A.
- Current Assignee: VERSALIS S.P.A.
- Current Assignee Address: IT
- Agency: Abel Law Group, LLP
- Priority: ITMO2012A1018 20120612
- International Application: PCT/IB2013/054746 WO 20130610
- International Announcement: WO2013/186691 WO 20131219
- Main IPC: C08F236/10
- IPC: C08F236/10 ; C08C19/44 ; C08L15/00 ; C08L9/00 ; C08L9/06 ; C08K3/04 ; C08K3/36 ; C08F212/08

Abstract:
A process for the preparation of a functionalized and branched elastomeric copolymer comprising the following steps: (a) anionic copolymerization of at least one conjugated diene monomer and at least one vinyl arene, in the presence of at least one hydrocarbon solvent, of at least one lithium-based initiator, and of at least one polar modifier, obtaining a solution comprising an elastomeric copolymer; (b) reacting at least 10% by weight, preferably from 20% by weight to 100 % by weight, of the polymeric chains present in the elastomeric copolymer obtained in step (a) with at least one compound having at least one functional group selected from: epoxides, ketones, esters, aldehydes, obtaining a solution comprising a functionalized elastomeric copolymer; (c) adding a quantity of lithium-based initiator to the solution obtained in step (b), from 1 to 4 times, preferably from 1.5 to 3 times, the molar quantity of lithium-based initiator used in step (a) and a compound of bromine having general formula (I): R—Br (I) wherein R represents a linear or branched C1-C30, preferably C2-C10, alkyl group, a C3-C30, preferably C4-C10, cycloalkyl group, a C6-C30, preferably C6-C12, aryl group.
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