公开(公告)号：US20150203611A1

公开(公告)日：2015-07-23

申请号：US14417928

申请日：2013-08-30

Applicant: Versalis S.P.A.

Inventor： Luca Soddu ,  Antonio Giuseppe Solito

IPC: C08F36/06

CPC classification number: C08F36/06 ,  C08C19/44 ,  C08F236/10 ,  C08F4/48

Abstract: Process for the preparation of diene polymers or random vinyl arene-diene copolymers which comprises (co) polymerizing, anionically, in the presence of at least one hydrocarbon solvent, at least one conjugated diene monomer and optionally at least one vinyl arene, in the presence of at least one lithium-based initiator, at least one aprotic polar compound, and at least one compound containing one or more functional groups of the acetylenic type. Said process allows diene polymers or random vinyl arene-diene copolymers to be obtained, which can be advantageously used in the production of tyres, in particular in the production of tyre treads. The diene polymers or the random vinyl arene-diene copolymers obtained through said process can also be used for the modification of plastic materials [for example, for obtaining high impact polystyrene (HIPS)].

Abstract translation: 二烯聚合物或无规乙烯基芳烃 - 二烯共聚物的制备方法，其包括（共）在至少一种烃溶剂存在下阴离子聚合至少一种共轭二烯单体和任选的至少一种乙烯基芳烃，在存在下 的至少一种锂基引发剂，至少一种非质子极性化合物和至少一种含有一个或多个炔属型官能团的化合物。 所述方法允许获得二烯聚合物或无规乙烯基芳烃 - 二烯共聚物，其可有利地用于生产轮胎，特别是在轮胎胎面的生产中。 通过所述方法获得的二烯聚合物或无规乙烯基芳烃 - 二烯共聚物也可用于塑料材料的改性（例如获得高抗冲聚苯乙烯（HIPS）]。

公开(公告)号：US10253116B2

公开(公告)日：2019-04-09

申请号：US15316617

申请日：2015-08-19

Applicant: Versalis S.P.A.

Inventor： Luca Soddu ,  Andrea Vallieri ,  Antonio Solito

IPC: C08F36/06 ,  C08F212/08 ,  C08F236/06 ,  C08F236/10 ,  C08F112/08

Abstract: Process for the preparation of a diene polymer or a random vinyl arene-diene copolymer comprising anionically (co)polymerizing at least one conjugated diene monomer, optionally in the presence of at least one vinyl arene, in the presence of at least one hydrocarbon solvent, at least one lithium-based initiator and at least one organic compound containing at least one nitrox- ide group having general formula (I) or (II): wherein: R1, R2, R3 and R4, mutually identical or different, represent a hydrogen atom; or are selected from C1-C20, preferably C1-C8, linear or branched alkyl groups optionally containing heteroatoms such as, for example, oxygen, nitrogen, sulphur, optionally substituted cycloalkyl groups, optionally substituted C1-C20, preferably C1-C8, linear or branched alkoxy groups, optionally substituted aryl groups; -x is an integer ranging from 0 to 7, preferably ranging from 4 to 5; -y is an integer ranging from 1 to 3, preferably ranging from 1 to 2.

公开(公告)号：US09447209B2

公开(公告)日：2016-09-20

申请号：US14417928

申请日：2013-08-30

Applicant: Versalis S.P.A.

Inventor： Luca Soddu ,  Antonio Giuseppe Solito

IPC: C08F4/46 ,  C08F36/00 ,  C08F12/02 ,  C08F36/06 ,  C08C19/44 ,  C08F236/10

CPC classification number: C08F36/06 ,  C08C19/44 ,  C08F236/10 ,  C08F4/48

Abstract: Process for the preparation of diene polymers or random vinyl arene-diene copolymers which comprises (co)polymerizing, anionically, in the presence of at least one hydrocarbon solvent, at least one conjugated diene monomer and optionally at least one vinyl arene, in the presence of at least one lithium-based initiator, at least one aprotic polar compound, and at least one compound containing one or more functional groups of the acetylenic type. Said process allows diene polymers or random vinyl arene-diene copolymers to be obtained, which can be advantageously used in the production of tires, in particular in the production of tire treads. The diene polymers or the random vinyl arene-diene copolymers obtained through said process can also be used for the modification of plastic materials [for example, for obtaining high impact polystyrene (HIPS)].

Abstract translation: 二烯聚合物或无规乙烯基芳烃 - 二烯共聚物的制备方法，其包括（共）在至少一种烃溶剂存在下阴离子聚合至少一种共轭二烯单体和任选的至少一种乙烯基芳烃，在存在下 的至少一种锂基引发剂，至少一种非质子极性化合物和至少一种含有一个或多个炔属型官能团的化合物。 所述方法允许获得二烯聚合物或无规乙烯基芳烃 - 二烯共聚物，其可有利地用于生产轮胎，特别是在轮胎胎面的生产中。 通过所述方法获得的二烯聚合物或无规乙烯基芳烃 - 二烯共聚物也可用于塑料材料的改性（例如获得高抗冲聚苯乙烯（HIPS）]。

公开(公告)号：US09534071B2

公开(公告)日：2017-01-03

申请号：US14404703

申请日：2013-06-10

Applicant: Versalis S.P.A.

Inventor： Luca Soddu

IPC: C08F236/10 ,  C08C19/44 ,  C08L15/00 ,  C08L9/00 ,  C08L9/06 ,  C08K3/04 ,  C08K3/36 ,  C08F212/08

CPC classification number: C08F236/10 ,  C08C19/44 ,  C08F212/08 ,  C08F2810/40 ,  C08K3/04 ,  C08K3/36 ,  C08L9/00 ,  C08L9/06 ,  C08L15/00 ,  C08L81/04 ,  C08L91/00 ,  C08F4/08

Abstract: A process for the preparation of a functionalized and branched elastomeric copolymer comprising the following steps: (a) anionic copolymerization of at least one conjugated diene monomer and at least one vinyl arene, in the presence of at least one hydrocarbon solvent, of at least one lithium-based initiator, and of at least one polar modifier, obtaining a solution comprising an elastomeric copolymer; (b) reacting at least 10% by weight, preferably from 20% by weight to 100 % by weight, of the polymeric chains present in the elastomeric copolymer obtained in step (a) with at least one compound having at least one functional group selected from: epoxides, ketones, esters, aldehydes, obtaining a solution comprising a functionalized elastomeric copolymer; (c) adding a quantity of lithium-based initiator to the solution obtained in step (b), from 1 to 4 times, preferably from 1.5 to 3 times, the molar quantity of lithium-based initiator used in step (a) and a compound of bromine having general formula (I): R—Br (I) wherein R represents a linear or branched C1-C30, preferably C2-C10, alkyl group, a C3-C30, preferably C4-C10, cycloalkyl group, a C6-C30, preferably C6-C12, aryl group.

Abstract translation: 一种制备官能化和支化的弹性体共聚物的方法，包括以下步骤：（a）至少一种共轭二烯单体和至少一种乙烯基芳烃在至少一种烃溶剂的存在下至少一种 锂基引发剂和至少一种极性改性剂，得到包含弹性体共聚物的溶液; （b）使在步骤（a）中获得的弹性体共聚物中存在的至少一种具有至少一个官能团的化合物选自至少10重量％，优选20重量％至100重量％的聚合物链 从：环氧化物，酮，酯，醛，得到包含官能化弹性体共聚物的溶液; （c）在步骤（b）中获得的溶液中加入一定量的锂基引发剂，为步骤（a）中使用的锂基引发剂的摩尔量和a（a）的摩尔量的1至4倍，优选1.5至3倍 具有通式（I）的溴化合物：R-Br（I）其中R表示直链或支链C 1 -C 30，优选C 2 -C 10烷基，C 3 -C 30，优选C 4 -C 10环烷基，C 6 -C30，优选C6-C12，芳基。

公开(公告)号：US20150183913A1

公开(公告)日：2015-07-02

申请号：US14404703

申请日：2013-06-10

Applicant: Versalis S.P.A.

Inventor： Luca Soddu

IPC: C08F236/10 ,  C08K3/04 ,  C08K3/36

CPC classification number: C08F236/10 ,  C08C19/44 ,  C08F212/08 ,  C08F2810/40 ,  C08K3/04 ,  C08K3/36 ,  C08L9/00 ,  C08L9/06 ,  C08L15/00 ,  C08L81/04 ,  C08L91/00 ,  C08F4/08

Abstract: A process for the preparation of a functionalized and branched elastomeric copolymer comprising the following steps: (a) anionic copolymerization of at least one conjugated diene monomer and at least one vinyl arene, in the presence of at least one hydrocarbon solvent, of at least one lithium-based initiator, and of at least one polar modifier, obtaining a solution comprising an elastomeric copolymer; (b) reacting at least 10% by weight, preferably from 20% by weight to 100% by weight, of the polymeric chains present in the elastomeric copolymer obtained in step (a) with at least one compound having at least one functional group selected from: epoxides, ketones, esters, aldehydes, obtaining a solution comprising a functionalized elastomeric copolymer; (c) adding a quantity of lithium-based initiator to the solution obtained in step (b), from 1 to 4 times, preferably from 1.5 to 3 times, the molar quantity of lithium-based initiator used in step (a) and a compound of bromine having general formula (I): R—Br (I) wherein R represents a linear or branched C1-C30, preferably C2-C10, alkyl group, a C3-C30, preferably C4-C10, cycloalkyl group, a C6-C30, preferably C6-C12, aryl group.

Abstract translation: 一种制备官能化和支化的弹性体共聚物的方法，包括以下步骤：（a）至少一种共轭二烯单体和至少一种乙烯基芳烃在至少一种烃溶剂的存在下至少一种 锂基引发剂和至少一种极性改性剂，得到包含弹性体共聚物的溶液; （b）使在步骤（a）中获得的弹性共聚物中存在的至少一种具有至少一个官能团的化合物选自至少10重量％，优选20重量％至100重量％的聚合物链 从：环氧化物，酮，酯，醛，得到包含官能化弹性体共聚物的溶液; （c）在步骤（b）中获得的溶液中加入一定量的锂基引发剂，为步骤（a）中使用的锂基引发剂的摩尔量和a（a）的摩尔量的1至4倍，优选1.5至3倍 具有通式（I）的溴化合物：R-Br（I）其中R表示直链或支链C 1 -C 30，优选C 2 -C 10烷基，C 3 -C 30，优选C 4 -C 10环烷基，C 6 -C30，优选C6-C12，芳基。