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US09586883B2 Aldehyde-selective wacker-type oxidation of unbiased alkenes 有权
醛类选择性瓦克型氧化无偏烯烃

Aldehyde-selective wacker-type oxidation of unbiased alkenes
Abstract:
This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising: (a) a dichloro-palladium complex; (b) a copper complex; (c) a source of nitrite; under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.
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