Invention Grant
- Patent Title: Aldehyde-selective wacker-type oxidation of unbiased alkenes
- Patent Title (中): 醛类选择性瓦克型氧化无偏烯烃
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Application No.: US14255049Application Date: 2014-04-17
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Publication No.: US09586883B2Publication Date: 2017-03-07
- Inventor: Zachary K. Wickens , Bill Morandi , Robert H. Grubbs , Kacper Skakuj , Sarah M. Bronner
- Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
- Applicant Address: US CA Pasadena
- Assignee: California Institute of Technology
- Current Assignee: California Institute of Technology
- Current Assignee Address: US CA Pasadena
- Agency: Baker & Hostetler LLP
- Main IPC: C07C45/34
- IPC: C07C45/34 ; C07C249/04 ; C07C253/00 ; C07C201/12 ; C07C205/44 ; C07C209/60 ; C07C213/00 ; C07C227/08 ; C07C51/373 ; C07C59/235 ; C07C211/48 ; C07C217/48 ; C07D301/22

Abstract:
This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising: (a) a dichloro-palladium complex; (b) a copper complex; (c) a source of nitrite; under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.
Public/Granted literature
- US20140316149A1 ALDEHYDE-SELECTIVE WACKER-TYPE OXIDATION OF UNBIASED ALKENES Public/Granted day:2014-10-23
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