Invention Grant
- Patent Title: Metal phosphide catalysts and methods for making the same and uses thereof
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Application No.: US15174691Application Date: 2016-06-06
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Publication No.: US09636664B1Publication Date: 2017-05-02
- Inventor: Susan Ellen Habas , Jun Wang , Daniel A. Ruddy , Frederick Raymond Gabriel Baddour , Joshua Schaidle
- Applicant: Alliance for Sustainable Energy, LLC
- Applicant Address: US CO Golden
- Assignee: Alliance for Sustainable Energy, LLC
- Current Assignee: Alliance for Sustainable Energy, LLC
- Current Assignee Address: US CO Golden
- Agent Michael A. McIntyre
- Main IPC: B01J27/19
- IPC: B01J27/19 ; C01B25/08 ; B01J27/185 ; B01J35/00 ; B01J37/08 ; C10G3/00

Abstract:
The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.
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