Invention Grant
- Patent Title: Systems and methods for separating chlorine-containing species from aqueous solutions of chlorine-containing species
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Application No.: US14062696Application Date: 2013-10-24
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Publication No.: US09718047B2Publication Date: 2017-08-01
- Inventor: Mark D. Moser , David A. Wegerer
- Applicant: UOP LLC
- Applicant Address: US IL Des Plaines
- Assignee: UOP LLC
- Current Assignee: UOP LLC
- Current Assignee Address: US IL Des Plaines
- Main IPC: B01J38/02
- IPC: B01J38/02 ; B01J23/96 ; B01J38/12 ; B01J38/18 ; C10K1/00 ; C10K1/10

Abstract:
Disclosed is a method for separating a chlorine-containing species from an aqueous solution of the chlorine-containing species in a catalytic hydrocarbon conversion process that includes the step of oxidizing a spent chloride-containing hydrocarbon conversion catalyst, the spent hydrocarbon conversion catalyst including a hydrocarbon residue formed thereon. The oxidizing forms a flue gas including chlorine-containing species, water, and oxides of carbon. The method further includes contacting the flue gas with a water scrubbing stream to dissolve at least a portion of the chlorine-containing species in the water scrubbing stream to form an aqueous acid solution and contacting the aqueous acid solution with a hygroscopic liquid to generate dehydrated hydrogen chloride gas. Still further, the method includes contacting the dehydrated hydrogen chloride gas with additional spent chloride-containing hydrocarbon conversion catalyst to sorb chlorine onto the additional spent chloride-containing hydrocarbon conversion catalyst.
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