Disclosed is a system and method of separating and collecting acid gas such as carbon dioxide in which the energy consumption in a stripping column for regenerating an absorbent may be reduced. In the system and method, the energy consumption may be reduced using heat generated during the acidic gas separation and collection processes. In the system and method, a low-temperature condensate from a condenser may be preheated by heat exchange with a high-temperature processed gas, and then supplied into the stripping column, thereby to reduce the heat duty of a reboiler and the energy consumption in the condenser for cooling. A partial flow of a carbon diode-absorbed absorbent from an absorber column may be preheated by heat exchange with high-temperature processed gas from an upper portion of the stripping column, and then supplied into the stripping column, thereby to further reduce the heat duty of the reboiler.