Invention Grant
- Patent Title: Composite polyamide membrane post treated with nitrious acid
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Application No.: US15030919Application Date: 2014-10-29
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Publication No.: US09808769B2Publication Date: 2017-11-07
- Inventor: Mou Paul , Abhishek Roy , Ian A. Tomlinson
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agent Edward W. Black
- International Application: PCT/US2014/062830 WO 20141029
- International Announcement: WO2015/084511 WO 20150611
- Main IPC: B01D67/00
- IPC: B01D67/00 ; B01D69/12 ; B01D71/56 ; B05D3/10

Abstract:
A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer, wherein the method includes: (i) applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer; (ii) treating the thin film polyamide layer with a polyfunctional arene compound; and (iii) exposing the thin film polyamide layer to nitrous acid; wherein the polar and non-polar solutions further comprises at least one of the following: (A) at least one of the solutions further comprises a tri-hydrocarbyl phosphate compound represented by Formula (I): and (B) the non-polar solution further comprises an acid-containing monomer comprising a C2-C20 hydrocarbon moiety substituted with at least one carboxylic acid functional group or salt thereof and at least one amine-reactive functional group.
Public/Granted literature
- US20160271567A1 COMPOSITE POLYAMIDE MEMBRANE POST TREATED WITH NITRIOUS ACID Public/Granted day:2016-09-22
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