Invention Grant
- Patent Title: Hydrogenation treatment catalyst for heavy hydrocarbon oil, and method for hydrogenation treatment of heavy hydrocarbon oil
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Application No.: US15022961Application Date: 2014-09-25
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Publication No.: US09908107B2Publication Date: 2018-03-06
- Inventor: Takayuki Osaki , Nobumasa Nakajima
- Applicant: Cosmo Oil Co., Ltd.
- Applicant Address: JP Tokyo
- Assignee: COSMO OIL CO., LTD.
- Current Assignee: COSMO OIL CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Panitch Schwarze Belisario & Nadel LLP
- Priority: JP2013-201801 20130927
- International Application: PCT/JP2014/075417 WO 20140925
- International Announcement: WO2015/046323 WO 20150402
- Main IPC: C10G65/04
- IPC: C10G65/04 ; B01J27/19 ; C10G45/08 ; B01J35/10 ; B01J35/00 ; B01J23/887 ; B01J21/12 ; B01J35/02

Abstract:
A hydrogenation treatment catalyst is provided for heavy hydrocarbon oil, in which a hydrogenation-active component is supported on a silica-containing porous alumina carrier containing 0.1% to 1.5% by mass of silica based on the carrier. The total pore volume is 0.55 to 0.75 mL/g. Of the total volume of pores having a pore diameter of 3 to 30 nm (1) 30% to 45% have a pore diameter of 5 to 10 nm, (2) 50% to 65% have a pore diameter of 10 to 15 nm, and (3) the total volume of pores having a pore diameter in a range of ±1 nm from the average pore diameter is 25% or more. The total volume of pores having a pore diameter of 30 nm or more is 3% or less. The average pore diameter of pores having a pore diameter of 10 to 30 nm is 10.5 to 13 nm.
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