Invention Grant
- Patent Title: Cleaning of liquid hydrocarbon streams by means of copper-containing sorbents
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Application No.: US15103805Application Date: 2014-11-05
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Publication No.: US09963644B2Publication Date: 2018-05-08
- Inventor: Frank Geilen , Stephan Peitz , Guido Stochniol , Markus Winterberg , Dietrich Maschmeyer , Armin Rix , Mathias Vogt
- Applicant: Evonik Degussa GmbH
- Applicant Address: DE Essen
- Assignee: Evonik Degussa GmbH
- Current Assignee: Evonik Degussa GmbH
- Current Assignee Address: DE Essen
- Agency: Michael Best & Friedrich LLP
- Priority: DE102013225724 20131212
- International Application: PCT/EP2014/073763 WO 20141105
- International Announcement: WO2015/086228 WO 20150618
- Main IPC: C10G25/00
- IPC: C10G25/00 ; C07C7/12 ; C07C7/13 ; C10G25/05 ; C10G53/08 ; C10G55/04 ; C10G57/00 ; C10G57/02 ; C10G67/06 ; B01J20/06 ; B01J20/08 ; B01J20/28 ; C10G53/14 ; B01J23/80 ; B01J35/00

Abstract:
The invention relates to a method for cleaning hydrocarbon mixtures, in which a contaminated hydrocarbon mixture comprising hydrocarbons having three to eight carbon atoms is at least partly freed of impurities by contacting with a solid sorbent, wherein the hydrocarbon mixture is exclusively in the liquid state during contact with the sorbent. The object of the invention is to specify a process for cleaning liquid C3 to C8 hydrocarbon mixtures, which is based on a readily available but non-carcinogenic sorbent and which achieves better purities compared to traditional molecular sieves. This object is achieved by using, as sorbents, solid materials of the following composition: copper oxide: 10% to 60% by weight (calculated as CuO); zinc oxide: 10% to 60% by weight (calculated as ZnO); aluminum oxide: 10% to 30% by weight (calculated as Al2O3); other substances: 0% to 5% by weight. Materials of this kind are otherwise used as catalysts in methanol synthesis.
Public/Granted literature
- US20160326442A1 CLEANING OF LIQUID HYDROCARBON STREAMS BY MEANS OF COPPER-CONTAINING SORBENTS Public/Granted day:2016-11-10
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