公开(公告)号：KR1020000039933A

公开(公告)日：2000-07-05

申请号：KR1019980055431

申请日：1998-12-16

Applicant: 국방과학연구소

Inventor： 이본수 ,  정규현 ,  전용구

IPC: C07C205/02

Abstract: PURPOSE: A dinitroamide salt is provided which is made from N-nitro-4-azaheptanic acid derivative having stability on preparation and safe-keeping. CONSTITUTION: A method for the preparation of a dinitroamide salt being improved comprises the steps of: adding a base as an ammonia, RNH2, (RR')NH, (RR'R)N, N2H4, N1-N10 amine organic base, (wherein, R, R', R are equal or different C1-C20 alkyl group) or metal hydroxylation, to a N-nitro-4-azaheptanic acid derivative followed chemical formula 1(O2N-N(CH2CH2Z)2); reacting a nitrating agent being selected from HNO3, NO3¬3AlCl4¬-, N2O5, NO2BF, NO2Cl, NO2Br, NO2F or (NO2+)2(S2O7¬2-); reacting a base being equal the base as a ammonia, RNH2, (RR')NH, (RR'R)N, N2H4, N1-N10 amine organic base, (wherein, R, R', R are equal or different C1-C20 alkyl group) or metal hydroxylation, or not, again. Wherein the following chemical formula 1 is O2N-N(CH2CH2Z)2(wherein, Z is selected of CN, CO2R or COR, R is alkyl group of C1-C10).

Abstract translation: 目的：提供由N-硝基-4-氮杂庚酸衍生物制备的二硝基酰胺盐，其在制备和保存时具有稳定性。 构成：改进的二硝基酰胺盐的制备方法包括以下步骤：加入碱作为氨，RNH2，（RR'）NH，（RR'R）N，N2H4，N1-N10胺有机碱，（ 根据化学式1（O 2 N-N（CH 2 CH 2 Z）2）的N-硝基-4-氮杂庚酸衍生物，其中R，R'，R等于或不同的C 1 -C 20烷基）或金属羟基化。 使选自HNO3，NO3_3AlCl4-，N2O5，NO2BF，NO2Cl，NO2Br，NO2F或（NO2 +）2（S2O7-2-）的硝化剂反应; 使碱作为氨，RNH2，（RR'）NH，（RR'R）N，N2H4，N1-N10胺有机碱（其中，R，R'，R等于或不同的C1- C20烷基）或金属羟基化反应。 其中以下化学式1是O 2 N-N（CH 2 CH 2 Z）2（其中，Z选自CN，CO 2 R或COR，R是C 1 -C 10的烷基）。

公开(公告)号：KR1020140018090A

公开(公告)日：2014-02-12

申请号：KR1020130021999

申请日：2013-02-28

Applicant: 국방과학연구소

Inventor： 김영규 ,  김진석 ,  정규현 ,  신문용 ,  김승희 ,  하태환 ,  이혜령 ,  김명학

IPC: C07D487/12 ,  C06B43/00

CPC classification number: C07D487/12 ,  C06B25/00 ,  C06B43/00

Abstract: The present invention relates to a hexaza[3.3.3]propellane compound denoted by chemical formula I capable of being used as a major skeleton structure of a new molecular explosive, and a method for preparing the same. In the chemical formula I: R is a foreign atom selected from H, oxygen, nitrogen, sulfur, or halogen, or C-20 alkyl, cycloalkyl, arylalkyl, or aryl capable of including an unsaturated group; and X is H2, O, or S.

Abstract translation: 本发明涉及能够用作新的分子炸药的主要骨架结构的化学式I所示的己烷[3.3.3]推进剂化合物及其制备方法。 在化学式I中：R是选自H，氧，氮，硫或卤素的外来原子，或可包含不饱和基团的C 20烷基，环烷基，芳基烷基或芳基; X是H 2，O或S.

公开(公告)号：KR1020010011940A

公开(公告)日：2001-02-15

申请号：KR1019990031560

申请日：1999-07-31

Applicant: 국방과학연구소

Inventor： 이본수 ,  정규현 ,  전용구

IPC: C07D259/00

Abstract: PURPOSE: The polyacylhexaazaisowurtzitane(AIW) derivatives, their production method and a method for producing hexanitro hexaazaisowurtzitane(HNIW) using the same are provided, thereby HNIW can be effectively produced in higher yield by using AIW easily produced. CONSTITUTION: The polyacylhexaazaisowurtzitane(AIW; polyacyl-2,4,6,8,10,12- hexaaza-tetracyclo £5.5.0.0(5.9).0(3.11)|dodecane) derivatives represented by the formula (I), in which X is RCO, wherein R is H or C1 to C10 alkyl, X' is H or R'CO, wherein R' is H or C1 to C10 alkyl, X'' is H or R''CO, wherein R'' is H or C1 to C10, and R, R' and R'' are the same or different, is produced by reacting hexaarylmethylhexaazaisowurtzitane(HArlW) with (R1CO)2O in the presence of metal catalyst, H2 and organic solvent; removing the solvent; and mixing the remnant with (R1CO)2O, (R2CO)2O, R2COX or R2COOH. The HNIW is produced by reacting AIW derivatives and their isomers with nitrogenating agents such as (R1CO)2O, (R2CO)2O, R2COX or R2COOH.

Abstract translation: 目的：提供多酰基六氮杂异纤锌矿型结构烷烃（AIW）衍生物，其制备方法和使用其制备六氮杂异纤锌矿型结构烷烃（HNIW）的方法，从而通过使用容易制备的AIW可以更高的产率有效地制备HNIW。 构成：由式（I）表示的聚酰基六氮杂异纤锌矿型结构烷烃（AIW;聚酰基-2,4,6,8,10,12-六氮杂 - 四环五十五.0.0.0（5.9）.0（3.11）|十二烷）衍生物，其中 X为RCO，其中R为H或C 1至C 10烷基，X'为H或R'CO，其中R'为H或C 1至C 10烷基，X“为H或R”CO，其中R“为 通过六芳基甲基六氮杂异纤锌矿型结构烷烃（HArlW）与（R1CO）2O在金属催化剂，H 2和有机溶剂的存在下反应制备R，R'和R“相同或不同。 除去溶剂; 并将剩余物与（R1CO）2O，（R2CO）2O，R2COX或R2COOH混合。 HNIW通过使AIW衍生物及其异构体与氮化剂如（R 1 CO）2 O，（R 2 CO）2 O，R 2 COX或R 2 COOH反应而生成。

公开(公告)号：KR100281825B1

公开(公告)日：2001-02-15

申请号：KR1019980055431

申请日：1998-12-16

Applicant: 국방과학연구소

Inventor： 이본수 ,  정규현 ,  전용구

IPC: C07C205/02

Abstract: 본 발명은 쉽게 구할 수 있으며, 보관 및 제조상에서 안정한, 다음 화학식 1을 갖는 N-니트로-4-아자헵탄산 유도체:
화학식 1
O
2 NN(CH
2 CH
2 Z)
2
(식 중에서, Z는 CN, CO
2 R 및 COR로 이루어진 군 중에서 선택된 전자 받게 작용기이며, 상기 R은 탄소수 1-10의 알킬기임)로부터 N,N-디니트로아미드염을 제조하는 방법, 및 상기 화학식 1의 N-니트로-4-아자헵탄산 유도체의 개선된 제조 방법을 제공한다.

公开(公告)号：KR101553876B1

公开(公告)日：2015-09-17

申请号：KR1020130021999

申请日：2013-02-28

Applicant: 국방과학연구소

Inventor： 김영규 ,  김진석 ,  정규현 ,  신문용 ,  김승희 ,  하태환 ,  이혜령 ,  김명학

IPC: C07D487/12 ,  C06B43/00

Abstract: 본발명은신규분자화약의주요골격구조로사용될수 있는하기화학식 (I)로표시되는헥사아자[3.3.3]프로펠레인화합물및 이의제조방법에관한것이다: [화학식 I]상기식 중, R은 H, 산소, 질소, 황, 할로겐등의이종원자또는불포화기를포함할수 있는 C~C의알킬, 시클로알킬, 아릴알킬또는아릴이고; X는 H, O 또는 S이다.

公开(公告)号：KR101259433B1

公开(公告)日：2013-04-30

申请号：KR1020120085155

申请日：2012-08-03

Applicant: 국방과학연구소

Inventor： 김영규 ,  김진석 ,  정규현 ,  신문용 ,  김승희 ,  하태환 ,  이혜령 ,  김명학

IPC: C07D487/18 ,  C06B25/04 ,  C06B43/00

CPC classification number: C07D487/18 ,  Y02P20/55

Abstract: PURPOSE: A method for preparing a hexaza[3.3.3]propellane compound is provided to induce smooth synthesis by applying proper protecting groups, and to ensure high latent energy. CONSTITUTION: A hexaza[3.3.3]propellane compound is denoted by chemical formula I. In the chemical formula I: R is H, C_1-C_20 alkyl, C_3-C_20 cycloalkyl, or C_7-C_20 wherein, the alkyl and aryl contains a heterogeneous atom or an unsaturated group selected from oxygen, nitrogen, sulfur, and halogen; and X is O or S. The compound is used for manufacturing a molecular explosive.

Abstract translation: 目的：提供一种制备十六氢[3.3.3]推进剂化合物的方法，以通过适当的保护基团诱导平滑合成，并确保高潜能。 构成：化学式I表示六氮杂[3.3.3]推进剂化合物。在化学式I中：R为H，C 1 -C 20烷基，C 3 -C 20环烷基或C 7 -C 20，其中烷基和芳基含有 异质原子或选自氧，氮，硫和卤素的不饱和基团; X为O或S.该化合物用于制造分子炸药。