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公开(公告)号：WO2012091296A1
公开(公告)日：2012-07-05
申请号：PCT/KR2011/008966
申请日：2011-11-23
CPC classification number: C08L25/08 , C08F285/00 , C08G77/04 , C08G77/80 , C08L51/04 , C08L55/02 , C08L83/00
Abstract: 본 발명에 따른 열가소성 수지 조성물은 고무질 중합체를 포함하는 코어; 및 상기 코어의 표면에 아크릴산 알킬 에스테르계 단량체 또는 메타크릴산 알킬 에스테르계 단량체, 불포화 니트릴계 단량체, 및 방향족 비닐계 단량체가 그라프트 중합되어 형성된 쉘을 포함하는 (A) 그라프트 공중합체 수지; 아크릴산 알킬 에스테르계 단량체 또는 메타크릴산 알킬 에스테르계 단량체, 방향족 비닐계 단량체 및 불포화 니트릴계 단량체를 중합시킨 공중합체, 및 아크릴산 알킬 에스테르계 단량체, 메타크릴산 알킬 에스테르계 단량체 또는 이들의 혼합물을 중합시킨 중합체 또는 공중합체를 포함하는 (B) 비그라프트 공중합체 수지; 및 (C) 실록산계 충격보강제를 포함하며, 충격강도 및 내스크래치성이 우수할 뿐만 아니라, 저온에서의 백탁 현상이 나타나지 않는다.
Abstract translation: 根据本发明，热塑性树脂组合物包括：包含橡胶聚合物的芯; （A）包含通过将丙烯酸烷基酯单体或甲基丙烯酸烷基酯单体，不饱和腈单体和芳族乙烯基单体接枝聚合到芯的表面上形成的壳的接枝共聚物树脂; （B）包含通过聚合丙烯酸烷基酯单体或甲基丙烯酸烷基酯单体，芳族乙烯基单体和不饱和腈单体而获得的共聚物的非接枝共聚物树脂，以及通过聚合丙烯酸烷基酯单体获得的聚合物或共聚物 甲基丙烯酸烷基酯单体或其混合物; 和基于硅氧烷的抗冲改性剂。 因此，本发明的组合物具有优异的冲击强度和耐划伤性，并且在低温下不会出现混浊的白色现象。
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Patent Agency Ranking
公开(公告)号：KR101333589B1
公开(公告)日：2013-11-28
申请号：KR1020100137669
申请日：2010-12-29
Applicant: 제일모직주식회사
IPC: C08L69/00 , C08K7/14 , C08K5/5415 , C08L23/28
CPC classification number: C08L69/00 , C08G77/04 , C08K5/42 , C08K7/14 , C08L27/18 , C08L83/04 , C08L2205/02 , C08L2205/03
Abstract: 본 발명은 (A)유리섬유 보강 폴리카보네이트 수지, (B)2종의 유기 실리콘계 화합물의 혼합물, (C)금속염계 난연제 및 (D)불소화 폴리올레핀계 수지로 구성되며, 상기 (B)2종의 유기 실리콘계 화합물의 혼합물은 (b1)실록산계 화합물 및 (b2)실리콘계 수지 조성물로 구성되는 유리섬유 보강 열가소성 수지 조성물에 관한 것이다.
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公开(公告)号：KR1020140099609A
公开(公告)日：2014-08-13
申请号：KR1020130012223
申请日：2013-02-04
Applicant: 제일모직주식회사
Abstract: A thermoplastic resin composition according to the present invention comprises: (A) a rubber-modified aromatic vinyl-based graft copolymer; (B) an aromatic vinyl-based non-graft copolymer polymerizing 75-90 wt% of aromatic vinyl-based monomer and 10-25 wt% of unsaturated nitrile-based monomer; (C) a modified aromatic vinyl-based non-graft copolymer polymerizing an acrylic-based monomer, the aromatic vinyl-based monomer, and the unsaturated nitrile-based monomer; and (D) polymeric amine-based antistatic agents. A molded product using the same is excellent not only in appearance quality and coloring properties, but also in antistatic performance.
Abstract translation: 本发明的热塑性树脂组合物含有：（A）橡胶改性的芳族乙烯基类接枝共聚物; （B）芳族乙烯基类非接枝共聚物，聚合75-90重量％的芳族乙烯基类单体和10-25重量％的不饱和腈基单体; （C）将丙烯酸系单体，芳香族乙烯系单体和不饱和腈系单体聚合的改性芳香族乙烯基类非接枝共聚物， 和（D）聚合胺基抗静电剂。 使用该成型体的成型体不仅在外观品质和着色性能方面优异，而且在抗静电性能方面也是优异的。
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公开(公告)号：KR1020130075793A
公开(公告)日：2013-07-08
申请号：KR1020110144032
申请日：2011-12-28
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to exclude a painting process, and to have excellent appearance. CONSTITUTION: A thermoplastic resin composition comprises a rubber-modified aromatic vinyl-based graft copolymer; a non-graft copolymer copolymerized of 75-90 wt% of an aromatic vinyl-based monomer and 10-25 wt% of an unsaturated nitrile monomer; and a modified aromatic vinyl-based non-graft copolymer polymerized of an acrylic monomer, an aromatic vinyl-based monomer, and an unsaturated nitrile-based monomer. The weight average molecular weight of the aromatic vinyl-based non-graft copolymer is 100,000-180,000 g/mol.
Abstract translation: 目的：提供热塑性树脂组合物以排除涂漆工艺，并具有优异的外观。 构成：热塑性树脂组合物包含橡胶改性的芳族乙烯基类接枝共聚物; 共聚有75-90重量％的芳族乙烯基类单体和10-25重量％的不饱和腈单体的非接枝共聚物; 和丙烯酸类单体，芳族乙烯基系单体和不饱和腈类单体聚合的改性芳香族乙烯基系非共聚物共聚物。 芳族乙烯基类非接枝共聚物的重均分子量为100,000〜180,000g / mol。
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公开(公告)号：KR1020120078583A
公开(公告)日：2012-07-10
申请号：KR1020110122132
申请日：2011-11-22
Applicant: 제일모직주식회사
CPC classification number: C08L51/003 , C08L33/12 , C08L33/20 , C08L51/06 , C08L83/04 , C08L2205/03
Abstract: PURPOSE: A thermoplastic resin composition is provided to have excellent impact resistance, and scratch resistance, and not occurring turbid phenomenon in low temperatures. CONSTITUTION: A thermoplastic resin composition comprises a graft copolymer resin, a non-graft copolymer resin, and a siloxane based impact reinforcing agent. The graft copolymer resin comprises a first graft copolymer resin of which average diameter of a rubber polymer is 0.18-0.30 micron, and a second graft copolymer resin of which average diameter of a rubber polymer is 0.10-0.17 micron, or a mixture thereof. The graft copolymer resin comprises a core comprising a rubber polymer, and a shell formed by graft-polymerization of a (meth)acrylic acid alkyl ester based monomer, an unsaturated nitrile based monomer, and an aromatic vinyl based monomer on the surface of the core.
Abstract translation: 目的：提供热塑性树脂组合物以具有优异的耐冲击性和耐刮擦性，并且在低温下不发生浑浊现象。 构成：热塑性树脂组合物包含接枝共聚物树脂，非接枝共聚物树脂和基于硅氧烷的冲击增强剂。 接枝共聚物树脂包括橡胶聚合物的平均直径为0.18-0.30微米的第一接枝共聚物树脂和橡胶聚合物的平均直径为0.10-0.17微米的第二接枝共聚物树脂或其混合物。 接枝共聚物树脂包括一种包含橡胶聚合物的芯和通过（甲基）丙烯酸烷基酯单体，不饱和腈基单体和芳族乙烯基类单体在芯的表面上接枝聚合形成的壳 。
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公开(公告)号：KR1020120075813A
公开(公告)日：2012-07-09
申请号：KR1020100137669
申请日：2010-12-29
Applicant: 제일모직주식회사
IPC: C08L69/00 , C08K7/14 , C08K5/5415 , C08L23/28
CPC classification number: C08L69/00 , C08G77/04 , C08K5/42 , C08K7/14 , C08L27/18 , C08L83/04 , C08L2205/02 , C08L2205/03
Abstract: PURPOSE: A glass fiber-reinforced polycarbonate resin composition is provided to have excellent flame retardance and impact resistance. CONSTITUTION: A glass fiber-reinforced polycarbonate resin composition comprises: a glass fiber-reinforced polycarbonate resin, a mixture of two kinds of organic silicone based compounds, and metal salt based flame retardant, and fluorinated polyolefin based resin. The mixture of two kinds of organic silicone based compound consists of a siloxane based compound, and silicon based resin composition. The glass fiber reinforced polycarbonate resin consists of 60-95 weight% of polycarbonate resin, and 5-40 weight% of glass fiber.
Abstract translation: 目的：提供玻璃纤维增强聚碳酸酯树脂组合物以具有优异的阻燃性和耐冲击性。 构成：玻璃纤维增强聚碳酸酯树脂组合物包括：玻璃纤维增强聚碳酸酯树脂，两种有机硅氧烷基化合物的混合物和金属盐类阻燃剂以及氟化聚烯烃类树脂。 两种有机硅氧烷基化合物的混合物由硅氧烷基化合物和硅基树脂组合物组成。 玻璃纤维增强聚碳酸酯树脂由60-95重量％的聚碳酸酯树脂和5-40重量％的玻璃纤维组成。
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