公开(公告)号：WO2013094844A1

公开(公告)日：2013-06-27

申请号：PCT/KR2012/006871

申请日：2012-08-28

Applicant: 제일모직주식회사 ,  장기보 ,  윤종태 ,  박형우

Inventor： 장기보 ,  윤종태 ,  박형우

IPC: C08L25/04 ,  C08L55/02 ,  C08L83/04 ,  C08L33/08

CPC classification number: C08L25/04 ,  C08G77/80 ,  C08L51/003 ,  C08L55/02 ,  C08L33/08 ,  C08L51/085

Abstract: 본 발명에 따른 열가소성 수지 조성물은 (A) 스티렌계 열가소성 수지; (B) 실록산계 충격보강제; 및 (C) 중량평균분자량이 1,000 g/mol 내지 10,000 g/mol인 아크릴계공중합체를 포함한다. 상기 열가소성 수지 조성물은 투명성, 내충격성, 유동성 및 컬러안정성이 우수할 뿐만 아니라, 저온에서의 백탁 현상이 나타나지 않는다.

Abstract translation: 本发明的热塑性树脂组合物含有：（A）苯乙烯类热塑性树脂组合物; （B）基于硅氧烷的抗冲改性剂; 和（C）重均分子量在1,000g / mol至10,000g / mol之间的丙烯酸共聚物。 热塑性树脂组合物不仅具有突出的透明性，耐冲击性，流动性和颜色稳定性，而且在低温下也不会发生白浊。

公开(公告)号：KR1020130071156A

公开(公告)日：2013-06-28

申请号：KR1020110138511

申请日：2011-12-20

Applicant: 제일모직주식회사

Inventor： 장기보 ,  윤종태 ,  박형우

IPC: C08L25/04 ,  C08L55/02 ,  C08L83/04 ,  C08L33/08

CPC classification number: C08L25/04 ,  C08G77/80 ,  C08L51/003 ,  C08L55/02 ,  C08L33/08 ,  C08L51/085

Abstract: PURPOSE: A thermoplastic resin composition is provided to have excellent transparency, impact strength, flowability, and color stability, and to prevent white turbidity at low temperature. CONSTITUTION: A thermoplastic resin composition comprises a styrene-based thermoplastic resin, a siloxane-based impact modifier; and an acrylic copolymer with a weight average molecular weight of 1,000-10,000 g/mol. The styrene-based thermoplastic resin comprises 5-35 wt% of a core-shell-structured graft copolymer resin which includes a core formed of a rubber polymer and a shell polymerized of an acrylate monomer, styrene monomer, and acrylonitrile-based monomer; and 65-95 wt% of a non-graft copolymer resin including a unit derived from the acrylate-based monomer.

Abstract translation: 目的：提供热塑性树脂组合物以具有优异的透明性，冲击强度，流动性和颜色稳定性，并防止低温下的白浊。 构成：热塑性树脂组合物包含苯乙烯类热塑性树脂，硅氧烷类抗冲改性剂， 和重均分子量为1,000〜10,000g / mol的丙烯酸共聚物。 苯乙烯类热塑性树脂包含5-35重量％的核 - 壳结构的接枝共聚物树脂，其包括由橡胶聚合物形成的芯和由丙烯酸酯单体，苯乙烯单体和丙烯腈 - 基单体聚合的壳; 和65-95重量％的包含衍生自丙烯酸酯类单体的单元的非接枝共聚物树脂。

公开(公告)号：KR101464250B1

公开(公告)日：2014-11-24

申请号：KR1020110138511

申请日：2011-12-20

Applicant: 제일모직주식회사

Inventor： 장기보 ,  윤종태 ,  박형우

IPC: C08L25/04 ,  C08L55/02 ,  C08L83/04 ,  C08L33/08

CPC classification number: C08L25/04 ,  C08G77/80 ,  C08L51/003 ,  C08L55/02 ,  C08L33/08 ,  C08L51/085

Abstract: 본 발명에 따른 열가소성 수지 조성물은 (A) 스티렌계 열가소성 수지; (B) 실록산계 충격보강제; 및 (C) 중량평균분자량이 1,000 g/mol 내지 10,000 g/mol인 아크릴계공중합체;를 포함한다. 상기 열가소성 수지 조성물은 투명성, 내충격성, 유동성 및 컬러안정성이 우수할 뿐만 아니라, 저온에서의 백탁 현상이 나타나지 않는다.

公开(公告)号：KR1020140099609A

公开(公告)日：2014-08-13

申请号：KR1020130012223

申请日：2013-02-04

Applicant: 제일모직주식회사

Inventor： 진성훈 ,  박강열 ,  박준홍 ,  박형우 ,  최정훈

IPC: C08L53/02 ,  C08L25/14 ,  C08L51/06 ,  C08J5/00

CPC classification number: C08L53/02 ,  C08J5/00 ,  C08L25/14 ,  C08L51/06

Abstract: A thermoplastic resin composition according to the present invention comprises: (A) a rubber-modified aromatic vinyl-based graft copolymer; (B) an aromatic vinyl-based non-graft copolymer polymerizing 75-90 wt% of aromatic vinyl-based monomer and 10-25 wt% of unsaturated nitrile-based monomer; (C) a modified aromatic vinyl-based non-graft copolymer polymerizing an acrylic-based monomer, the aromatic vinyl-based monomer, and the unsaturated nitrile-based monomer; and (D) polymeric amine-based antistatic agents. A molded product using the same is excellent not only in appearance quality and coloring properties, but also in antistatic performance.

Abstract translation: 本发明的热塑性树脂组合物含有：（A）橡胶改性的芳族乙烯基类接枝共聚物; （B）芳族乙烯基类非接枝共聚物，聚合75-90重量％的芳族乙烯基类单体和10-25重量％的不饱和腈基单体; （C）将丙烯酸系单体，芳香族乙烯系单体和不饱和腈系单体聚合的改性芳香族乙烯基类非接枝共聚物， 和（D）聚合胺基抗静电剂。 使用该成型体的成型体不仅在外观品质和着色性能方面优异，而且在抗静电性能方面也是优异的。

公开(公告)号：KR1020130075793A

公开(公告)日：2013-07-08

申请号：KR1020110144032

申请日：2011-12-28

Applicant: 제일모직주식회사

Inventor： 진성훈 ,  박형우 ,  박준홍 ,  윤종태 ,  이우균 ,  신남호 ,  이성대 ,  장기보

IPC: C08L51/04 ,  C08L25/12 ,  C08L55/02 ,  C08J5/00

Abstract: PURPOSE: A thermoplastic resin composition is provided to exclude a painting process, and to have excellent appearance. CONSTITUTION: A thermoplastic resin composition comprises a rubber-modified aromatic vinyl-based graft copolymer; a non-graft copolymer copolymerized of 75-90 wt% of an aromatic vinyl-based monomer and 10-25 wt% of an unsaturated nitrile monomer; and a modified aromatic vinyl-based non-graft copolymer polymerized of an acrylic monomer, an aromatic vinyl-based monomer, and an unsaturated nitrile-based monomer. The weight average molecular weight of the aromatic vinyl-based non-graft copolymer is 100,000-180,000 g/mol.

Abstract translation: 目的：提供热塑性树脂组合物以排除涂漆工艺，并具有优异的外观。 构成：热塑性树脂组合物包含橡胶改性的芳族乙烯基类接枝共聚物; 共聚有75-90重量％的芳族乙烯基类单体和10-25重量％的不饱和腈单体的非接枝共聚物; 和丙烯酸类单体，芳族乙烯基系单体和不饱和腈类单体聚合的改性芳香族乙烯基系非共聚物共聚物。 芳族乙烯基类非接枝共聚物的重均分子量为100,000〜180,000g / mol。