公开(公告)号：WO2018152076A1

公开(公告)日：2018-08-23

申请号：PCT/US2018/017912

申请日：2018-02-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： GRYSKA, Stefan H. ,  CHATTERJEE, Joon ,  GOPALAKRISHNAN, Deepti ,  GRIESGRABER, George W. ,  KREPSKI, Larry R. ,  GADDAM, Babu N.

IPC: C09J4/06 ,  C09J7/38

Abstract: Described is a polymerizable polymer composition compri a) a copolymerizable macromer; b) a (meth)acrylate ester monomer; and c) a polyfunctional type I photoinitiator.

公开(公告)号：WO2014164000A1

公开(公告)日：2014-10-09

申请号：PCT/US2014/019767

申请日：2014-03-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： WEIKEL, Arlin L. ,  GADDAM, Babu N. ,  KREPSKI, Larry R. ,  MAHONEY, Wayne S. ,  CLAPPER, Jason D.

IPC: C09J133/06

CPC classification number: C09J133/08 ,  C08L63/00 ,  C08L2312/00 ,  C09J7/385 ,  C09J133/068 ,  Y10T428/2809

Abstract: Adhesive compositions and methods of preparing an adhesive composition are described. The method comprises providing a syrup composition comprising a free-radically polymerizable solvent monomer and a solute (meth)acrylic copolymer, and radiation curing the syrup composition in the absence of an ionic photoacid generator. The solute (meth)acrylic copolymer comprises epoxy-functional groups, acid-functional groups, or a combination thereof. In some embodiments, an epoxy resin having on average greater than one polymerizable epoxy group per molecule or an acid comprising at least two carboxylic acid groups is utilized. The epoxy-functional groups and acid-functional groups of the (meth)acrylic copolymer or the adhesive composition can readily crosslink in the absence of an ionic photoacid generator (PAG).

Abstract translation: 描述了粘合剂组合物和制备粘合剂组合物的方法。 该方法包括提供包含可自由基聚合的溶剂单体和溶质（甲基）丙烯酸共聚物的糖浆组合物，并且在不存在离子型光酸产生剂的情况下辐射固化糖浆组合物。 溶质（甲基）丙烯酸共聚物包含环氧官能团，酸官能团或其组合。 在一些实施方案中，使用每分子平均具有大于1个可聚合环氧基团的环氧树脂或包含至少两个羧酸基团的酸。 （甲基）丙烯酸共聚物或粘合剂组合物的环氧官能团和酸官能团可以在不存在离子光酸产生剂（PAG）的情况下容易地交联。

公开(公告)号：WO2014093014A1

公开(公告)日：2014-06-19

申请号：PCT/US2013/071883

申请日：2013-11-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YURT, Serkan ,  CLAPPER, Jason D. ,  BEHLING, Ross E. ,  CAMPBELL, Christopher J. ,  ELLIS, Mark F. ,  KREPSKI, Larry R. ,  FORNOF, Ann R. ,  GADDAM, Babu N. ,  DIZIO, James P.

IPC: C09J4/00 ,  C09J133/00

CPC classification number: C09J133/08 ,  C08F220/20 ,  C08F2220/1891 ,  C08F2220/343 ,  C08L2312/00 ,  C09J4/00 ,  C09J7/20 ,  C09J133/066 ,  C09J133/14 ,  C09J143/04 ,  C09J2433/00 ,  Y10T428/2891

Abstract: The disclosure describes a curable composition comprising a first oligomer having a plurality of polymerizable groups; a second component comprising alkylene oxide repeat units and terminal polymerizable groups, a solvent monomer component; and a photoinitiator. The curable composition may be used as an adhesive in optical applications.

Abstract translation: 本公开描述了一种可固化组合物，其包含具有多个可聚合基团的第一低聚物; 包含环氧烷重复单元和末端可聚合基团的第二组分，溶剂单体组分; 和光引发剂。 可固化组合物可用作光学应用中的粘合剂。

公开(公告)号：WO2014074427A1

公开(公告)日：2014-05-15

申请号：PCT/US2013/068207

申请日：2013-11-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  FORNOF, Ann R. ,  CRAIG, Bradley D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan ,  OXMAN, Joel D.

IPC: C08F230/08 ,  A61K6/083 ,  C09D4/00

CPC classification number: C08K5/5455 ,  C07F7/1844 ,  C07F7/1892 ,  C08F2/38 ,  C08F230/08 ,  C08F2438/01 ,  C08F2438/03 ,  C09J4/06

Abstract: Addition-fragmentation agents of the formula are disclosed having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least two surface-binding functional groups that associate with the surface of a substrate.

Abstract translation: 公开了具有以下官能团的式的加成 - 裂解剂：1）可以切割和改性以减轻应变的不稳定加成断裂基团，2）与底物表面缔合的至少两个表面结合官能团 。

公开(公告)号：WO2013130238A1

公开(公告)日：2013-09-06

申请号：PCT/US2013/025268

申请日：2013-02-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： FORNOF, Ann R. ,  GADDAM, Babu N. ,  LEE, Hae-Seung ,  CLAPPER, Jason, D. ,  KREPSKI, Larry R. ,  CARUSO, Mary M. ,  YURT, Serkan

IPC: C08F8/30

CPC classification number: C08F222/10 ,  C09J7/385 ,  C09J133/14 ,  C08F2220/1858 ,  C08F220/06 ,  C08F2220/343

Abstract: The present disclosure provides an ionically crosslinkable composition comprising a (meth)acrylate copolymer component having pendant acid functional groups and pendant photobase functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that ionically crosslinks the copolymer.

Abstract translation: 本公开提供了包含具有侧链酸官能团和侧基光基官能团的（甲基）丙烯酸酯共聚物组分的可离子交联组合物。 在曝光时，侧基基团光聚合以提供使该共聚物离子交联的侧基胺基。

公开(公告)号：WO2011087621A2

公开(公告)日：2011-07-21

申请号：PCT/US2010/059033

申请日：2010-12-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WANG, Yizhong ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  ZHU, Peiwang ,  LEWANDOWSKI, Kevin M., ,  HOLMES, Brian N.

Inventor： WANG, Yizhong ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  ZHU, Peiwang ,  LEWANDOWSKI, Kevin M., ,  HOLMES, Brian N.

IPC: A61K6/083

CPC classification number: A61K6/083 ,  A61C5/70 ,  A61C13/26 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  C08F220/60 ,  C08F2220/606 ,  C08L33/00

Abstract: Presently described are curable dental compositions comprising a polymerizable ionic liquid. The polymerizable ionic liquid comprises one or more ethylenically unsaturated (e.g. free-radically polymerizable) groups. Various embodiments of curable dental compositions are described. In some embodiments, the polymerizable ionic liquid is a monofunctional polymerizable ionic liquid comprising an ethylenically unsaturated group. In other embodiments, the polymerizable ionic liquid is a multifunctional polymerizable ionic liquid comprising at least two ethylenically unsaturated groups. The curable dental compositions describe herein can be utilized as dental primers, dental adhesives, dental sealants, and dental composites. In many embodiments, the curable dental compositions further comprise an initiator such as a photoinitiator.

Abstract translation: 目前描述的是包含可聚合离子液体的可固化牙科组合物。 可聚合离子液体包含一种或多种烯属不饱和（例如可自由基聚合的）基团。 描述了可固化牙科组合物的各种实施方案。 在一些实施方案中，可聚合离子液体是包含烯属不饱和基团的单官能可聚合离子液体。 在其它实施方案中，可聚合离子液体是包含至少两个烯键式不饱和基团的多官能可聚合离子液体。 本文描述的可治疗牙科用组合物可用作牙科引物，牙科粘合剂，牙科密封剂和牙科复合材料。 在许多实施方案中，可固化牙科组合物还包含引发剂如光引发剂。

公开(公告)号：WO2015057413A1

公开(公告)日：2015-04-23

申请号：PCT/US2014/059236

申请日：2014-10-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： FORNOF, Ann R. ,  MOSER, William H. ,  ABUELYAMAN, Ahmed S. ,  JOLY, Guy D. ,  KREPSKI, Larry R. ,  YURT, Serkan

IPC: C08G75/00 ,  A61C5/04 ,  A61K6/083 ,  C07C323/54 ,  C09D4/00 ,  C08F230/08 ,  C08L51/00

CPC classification number: C07C323/54 ,  A61C5/50 ,  A61K6/0073 ,  A61K6/083 ,  C07C323/12 ,  C08F2/38 ,  C08F290/067 ,  C08F2220/1858 ,  C08F2222/102 ,  C08F2222/225 ,  C08F2230/085 ,  C08F2438/03 ,  C08G75/00 ,  C08L35/02 ,  C08L51/08 ,  C09D4/00 ,  C09D133/14 ,  C09D135/02 ,  A61K6/0023 ,  C08L33/10 ,  A61K6/0017

Abstract: A Addition-fragmentation oligomers containing allylic disulfide groups are described. The oligomers may be added to polymerizable compositions to provide labile crosslinks that can cleave and reform during the polymerization process.

Abstract translation: 描述了含有烯丙基二硫化物基团的加成 - 裂解低聚物。 可以将低聚物加入到可聚合组合物中以提供在聚合过程中可以切割和改性的不稳定交联。

公开(公告)号：WO2013028397A2

公开(公告)日：2013-02-28

申请号：PCT/US2012/050718

申请日：2012-08-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan

Inventor： JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan

IPC: A61K6/083

CPC classification number: A61K6/083 ,  A61C19/003 ,  A61K6/0023 ,  A61K6/0835 ,  C08L33/08 ,  C08L33/10

Abstract: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.

Abstract translation: 公开了包含加成 - 断裂剂和可固化牙科树脂的可固化牙科用组合物。

公开(公告)号：WO2012177337A1

公开(公告)日：2012-12-27

申请号：PCT/US2012/037735

申请日：2012-05-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  MAHONEY, Wayne S. ,  WEIKEL, Arlin L. ,  KREPSKI, Larry R. ,  GADDAM, Babu N.

Inventor： MAHONEY, Wayne S. ,  WEIKEL, Arlin L. ,  KREPSKI, Larry R. ,  GADDAM, Babu N.

IPC: C08L33/06 ,  C08L63/00 ,  C09J133/06 ,  C09J163/00 ,  C08G59/68

CPC classification number: C09J133/14 ,  C08G59/3209 ,  C08G59/68 ,  C08L33/062 ,  C08L63/00 ,  C09J7/38 ,  C09J7/385 ,  C09J133/062 ,  C09J163/00 ,  Y10T428/287

Abstract: A pre-adhesive composition is described comprising an epoxy-functional (meth)acryloyl copolymer and epoxy resin, which when crosslinked using an ionic photoacid generator (PAG) provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles having desirable properties.

Abstract translation: 描述了包含环氧官能的（甲基）丙烯酰基共聚物和环氧树脂的预粘合剂组合物，当使用离子型光酸产生剂（PAG）交联时，提供具有所需性质的压敏粘合剂和压敏粘合剂制品。

公开(公告)号：WO2012112304A1

公开(公告)日：2012-08-23

申请号：PCT/US2012/023475

申请日：2012-02-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： JOLY, Guy D. ,  KREPSKI, Larry R. ,  FORNOF, Anne R. ,  YURT, Serkan ,  GADDAM, Babu N. ,  ABUELYAMAN, Ahmed S. ,  KROPP, Michael A.

IPC: C07C271/16 ,  C07C69/593

CPC classification number: C08K5/205 ,  A61K6/083 ,  C07C67/14 ,  C07C67/26 ,  C07C69/593 ,  C07C271/16 ,  C08K3/22 ,  C08K3/36 ,  C08K5/11 ,  C08K5/12 ,  C09D133/08 ,  C08L33/10 ,  C08L33/08

Abstract: Addition-fragmentation agents of the formula are disclosed formula (I): wherein R 1 , R 2 and R 3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R 1 , R 2 and R 3 is Zm-Q-, Q is a linking group have a valence of m +1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X 1 is independently -O- or -NR 4 -, where R 4 is H or C 1 -C 4 alkyl, and n is 0 or 1.

Abstract translation: 式（I）的加成裂解剂是公开的：其中R1，R2和R3各自独立地为ZQ-，（杂）烷基或（杂）芳基，条件是R1，R2中的至少一个 且R 3为Z m-Q-，Q为连接基团，其m价为m + 1; Z为烯键式不饱和可聚合基团，m为1至6; 每个X1独立地是-O-或-NR4-，其中R4是H或C1-C4烷基，n是0或1。