Abstract:
Non-silicone urea-based adhesives are disclosed which are prepared by the polymerization of reactive oligomers with the general formula X-B-X, where X is an ethylenically unsaturated group and B is a unit free of silicone and containing urea groups. The reactive oligomers can be prepared from polyamines through chain extension reactions using diaryl carbonates followed by capping reactions. Adhesive articles, including optical adhesive articles may be prepared using the disclosed non-silicone urea-based adhesives.
Abstract:
inhibiting formation of optical artifacts in a multi-layer film polarizer of an optical imaging assembly that includes a polarizing beam splitter. The beam splitter may include a multilayer reflective polarizing film having at least two materials, one of which may exhibit birefringence after uniaxial orientation; an adhesive disposed on the multilayer reflective polarizing film; and at least a first prism disposed on the adhesive. The adhesive may include a plasticizer for inhibiting formation of optical artifacts in the polarizing film.
Abstract:
An optical construction includes a reflective polarizer and an optical film. The optical film includes a matrix and a plurality of first particles dispersed in the matrix. Each of the matrix and the plurality of first particles includes a silicone polyoxamide and an acrylate polymer. For substantially normally incident light and for at least a first wavelength in a first wavelength range, the reflective polarizer reflects about 60% for a first polarization state and transmits about 40% for an orthogonal second polarization state. For at least a second wavelength in a second wavelength range, each of the reflective polarizer and the optical film transmits about 60% of an incident light for each of the first and second polarization states. For at least the first wavelength, optical film has an optical haze and a depolarization ratio. A ratio of the depolarization ratio to the optical haze is less than 0.1.
Abstract:
This disclosure provides novel adhesive compositions comprising a highly crosslinked and plasticized low T g (meth)acrylic copolymer that are self-wetting when applied to a substrate, and peelable therefrom.
Abstract:
Provided is a method of forming a fibrin hydrogel composition, the method including providing a fibrin hydrogel or precursor thereof, comprising fibrin hydrogel forming salt. The fibrin hydrogel forming salt concentration is greater than or equal to the threshold concentration to form a fibrin hydrogel. The method further includes combining the fibrin hydrogel with a carrier material. The concentration of the carrier material typically ranges from 0.1 to about 50 wt.-%. The method further includes reducing the salt concentration below the threshold concentration to form a fibrin hydrogel.
Abstract:
Provided is a method of forming a fibrinogen hydrogel composition, the method including providing a fibrinogen hydrogel or precursor thereof, comprising fibrinogen hydrogel forming salt. The fibrinogen hydrogel forming salt concentration is greater than or equal to the threshold concentration to form a fibrinogen hydrogel. The method further includes denaturing the fibrinogen hydrogel such as by heating. The method optionally further includes combining the fibrinogen hydrogel with a carrier material. When present, the concentration of the carrier material typically ranges from 0.1 to about 50 wt.-%. The method further includes reducing the salt concentration below the threshold concentration to form a fibrinogen hydrogel.
Abstract:
Polymeric materials are disclosed herein that include a reaction product of components comprising: a) a first amine component having at least two and at most three primary amino groups, secondary amino groups, or a mixture thereof, with the proviso that the first amine component is not a silicone diamine; b) a second amine component having (i) greater than three primary amino groups, or (ii) at least three primary amino groups and a plurality of secondary amino groups, wherein the second amine component is a polymeric material having a carbon backbone or a polymeric material having a carbon backbone with a plurality of catenated nitrogen atoms; and c) an oxalate ester.
Abstract:
Polymeric materials are disclosed herein that include a Polymer A, a Polymer B, and an oxalate ester or reaction product thereof. Polymer A contains electrophilic reactive groups, and Polymer B contains nucleophilic groups. In certain embodiments, the polymeric materials are free-flowing liquids at 100% solids that can be used, for example, as topical skin adhesives.
Abstract:
A self-wetting adhesive composition is described comprising the reaction product of a low T g (meth)acrylate solute copolymer component; a low T g solvent monomer solvent monomer component comprising low T g monomers, a multifunctional acrylate; and a polymerizable siloxane copolymer having at least one polydiorganosiloxane segment and at least on oxyalkylene segment.
Abstract:
The disclosure describes a curable composition comprising a first oligomer having a plurality of polymerizable groups; a second component comprising alkylene oxide repeat units and terminal polymerizable groups, a solvent monomer component; and a photoinitiator. The curable composition may be used as an adhesive in optical applications.