2.
    发明专利
    未知

    公开(公告)号:DE19704482A1

    公开(公告)日:1998-08-13

    申请号:DE19704482

    申请日:1997-02-06

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing halogen-free, reactive polyisobutene with a terminal double-bond content of over 50 mol % and an average molecular weight of 2,800 - 10,000 Dalton by cationic polymerization of isobutene or isobutene-containing hydrocarbon mixtures in a liquid phase, wherein polmerization is carried out at a temperature of -30 DEG C to +40 DEG C in the presence of a heterogeneous polymerization catalyst from one or several oxides of the elements of the 5th and 6th subgroup of the periodic table of elements or in the presence of a heterogeneous polymerization catalyst containing one or more oxidic compounds of one or more elements of the 5th and 6th subgroup of the periodic table of elements on an oxygen-containing zircon compound of various non-zeolitic oxidic supporting material, wherein said catalyst contains no technically active quantities of halogen.

    5.
    发明专利
    未知

    公开(公告)号:DE19734176A1

    公开(公告)日:1999-02-11

    申请号:DE19734176

    申请日:1997-08-07

    Applicant: BASF AG

    Abstract: A process is disclosed for preparing halogen-free, reactive polyisobutylene with a content of terminal double bonds of more than 50 % by moles and an average molecular weight Mn of 500 to 5000 daltons by cationic polymerisation of isobutylene or isobutylene-containing hydrocarbon mixtures in the liquid phase. Polymerisation is carried out at a temperature of between -40 and +10 DEG C in the presence of a molybdate or wolframate heteropolyacid.

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